Allyl glycidyl ether polymer

Base Information

• Chemical Name: Allyl glycidyl ether polymer
• CAS No.: 25639-25-2
• Molecular Formula: C₆H₁₀O₂
• Molecular Weight: 114.144
• Mol file: 25639-25-2.mol

Synonyms:Oxirane,[(2-propenyloxy)methyl]-, homopolymer (9CI); Propane, 1-(allyloxy)-2,3-epoxy-,polymers (8CI); 1-Allyloxy-2,3-epoxypropane homopolymer; Allyl glycidyl etherhomopolymer; Allyl glycidyl ether oligomer; Allyl glycidyl ether polymer; EpiolA; Neoallyl G; PAGE 10; Poly(allyl glycidyl ether);Poly[(allyloxymethyl)oxirane]; Poly[1-(allyloxy)-2,3-epoxypropane]; SantolinkXI

Chemical Property of Allyl glycidyl ether polymer

Chemical Property:

• Boiling Point: 189°Cat760mmHg
• Flash Point: 76.1°C
• Density: 1.095g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Allyl glycidyl ether polymer

There total 49 articles about Allyl glycidyl ether polymer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.17%

allyl alcohol (107-18-6) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → Allyl glycidyl ether (106-92-3,25639-25-2,90907-93-0)

Guidance literature:

allyl alcohol; epichlorohydrin; With trifluorormethanesulfonic acid; sulfuric acid; at 45 - 55 ℃; for 5h; Molecular sieve;

With N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide; at 40 - 45 ℃; for 3h; Reagent/catalyst; Temperature;

Reference yield: 94.0%

Toluene-4-sulfonic acid (R)-3-allyloxy-2-hydroxy-propyl ester (128495-90-9) → (+)-3-(allyloxy)-1,2-epoxypropane (95043-55-3,25639-25-2,90907-93-0)

Guidance literature:

With sodium hydride; In tetrahydrofuran; for 0.5h; Ambient temperature;

DOI:10.1021/jo00303a026

Reference yield: 87.0%

Acetic acid (S)-1-allyloxymethyl-2-(toluene-4-sulfonyloxy)-ethyl ester (128572-87-2) → (-)-3-(allyloxy)-1,2-epoxypropane (95043-56-4,25639-25-2,90907-93-0)

Guidance literature:

With potassium hydroxide; In methanol; for 1h; Ambient temperature;

DOI:10.1021/jo00303a026

upstream raw materials:

peracetic acid

Allyl ether

allyl alcohol

epichlorohydrin

Downstream raw materials:

(-)-3-(allyloxy)-1,2-epoxypropane

1-allyloxy-3-(4-methyl-piperidin-1-yl)-propan-2-ol

<(Allyloxy)-methyl>-18-crown-6

(+)-3-(allyloxy)-1,2-epoxypropane

Refernces

• 1、 Lansing, Markus,Engler, Hauke,Leuther, Tobias M.,Neud?rfl, J?rg-M.,Berkessel, Albrecht. "Titanium cis-1,2-Diaminocyclohexane Salalen Catalysts of Outstanding Activity and Enantioselectivity for the Asymmetric Epoxidation of Nonconjugated Terminal Olefins with Hydrogen Peroxide". . p. 3706 - 3709. Retrieved 2016.
• 2、 Kazemnejadi, Milad,Mahmoudi, Boshra,Sharafi, Zeinab,Nasseri, Mohammad Ali,Allahresani, Ali,Esmaeilpour, Mohsen. "Synthesis and characterization of a new poly α-amino acid Co(II)-complex supported on magnetite graphene oxide as an efficient heterogeneous magnetically recyclable catalyst for efficient free-coreductant gram-scale epoxidation of olefins with molecular oxygen". . p. 59 - 69. Retrieved 2019/06/13.
• 3、 Cleveland, Alexander H.,Fronczek, Frank R.,Kartika, Rendy. "Synthesis of Vicinal Dichlorides via Activation of Aliphatic Terminal Epoxides with Triphosgene and Pyridine". . p. 3367 - 3377. Retrieved 2018/03/26.