tert-Butyl-dimethyl-((1R,2R)-2-methyl-5-phenylsulfanyl-cyclohepta-3,5-dienyloxy)-silane

Base Information

Chemical Name:tert-Butyl-dimethyl-((1R,2R)-2-methyl-5-phenylsulfanyl-cyclohepta-3,5-dienyloxy)-silane
CAS No.:1019753-79-7
Molecular Formula:C₂₀H₃₀OSSi
Molecular Weight:346.609
Hs Code.:

Synonyms:tert-Butyl-dimethyl-((1R,2R)-2-methyl-5-phenylsulfanyl-cyclohepta-3,5-dienyloxy)-silane

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Chemical Property of tert-Butyl-dimethyl-((1R,2R)-2-methyl-5-phenylsulfanyl-cyclohepta-3,5-dienyloxy)-silane

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Technology Process of tert-Butyl-dimethyl-((1R,2R)-2-methyl-5-phenylsulfanyl-cyclohepta-3,5-dienyloxy)-silane

There total 4 articles about tert-Butyl-dimethyl-((1R,2R)-2-methyl-5-phenylsulfanyl-cyclohepta-3,5-dienyloxy)-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1019753-49-1
C₂₀H₂₂O₃S₂

: 69739-34-0
t-butyldimethylsiyl triflate

: 1019753-79-7
tert-Butyl-dimethyl-((1R,2R)-2-methyl-5-phenylsulfanyl-cyclohepta-3,5-dienyloxy)-silane

Guidance literature:: C₂₀H₂₂O₃S₂; t-butyldimethylsiyl triflate; With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 25 ℃; for 0.5h;

With trimethylaluminum; In hexane; dichloromethane; at -78 - 25 ℃; Further stages.;
DOI:10.1021/jo702353e

Reference yield:

: 1019753-37-7
((1R,2S)-3-Benzenesulfonyl-2-methyl-5-phenylsulfanyl-cyclohept-4-enyloxy)-tert-butyl-dimethyl-silane

: 1019753-79-7
tert-Butyl-dimethyl-((1R,2R)-2-methyl-5-phenylsulfanyl-cyclohepta-3,5-dienyloxy)-silane

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; triethylamine; In dichloromethane; Heating;
DOI:10.1002/anie.200350955

Reference yield:

: 882-33-7
diphenyldisulfane

: 1019753-79-7
tert-Butyl-dimethyl-((1R,2R)-2-methyl-5-phenylsulfanyl-cyclohepta-3,5-dienyloxy)-silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: tetrahydrofuran / -78 °C

1.2: tetrahydrofuran / -78 - 20 °C

2.1: trimethylsilyl triflate; (C₂H₅)3N / CH₂Cl₂ / Heating

With trimethylsilyl trifluoromethanesulfonate; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.200350955