rac-(T-4)-chloro(η5-pentamethylcyclopentadienyl)(2-phenylene-κC(1'),pyridine-κN)rhodium(III)

Base Information

• Chemical Name: rac-(T-4)-chloro(η5-pentamethylcyclopentadienyl)(2-phenylene-κC(1'),pyridine-κN)rhodium(III)
• CAS No.: 945491-50-9
• Molecular Formula: C₂₁H₂₃ClNRh
• Molecular Weight: 427.779

Synonyms:rac-(T-4)-chloro(η5-pentamethylcyclopentadienyl)(2-phenylene-κC(1'),pyridine-κN)rhodium(III)

Chemical Property of rac-(T-4)-chloro(η5-pentamethylcyclopentadienyl)(2-phenylene-κC(1'),pyridine-κN)rhodium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of rac-(T-4)-chloro(η5-pentamethylcyclopentadienyl)(2-phenylene-κC(1'),pyridine-κN)rhodium(III)

There total 4 articles about rac-(T-4)-chloro(η5-pentamethylcyclopentadienyl)(2-phenylene-κC(1'),pyridine-κN)rhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-phenylpyridine (1008-89-5) + C22H22ClN2Rh → 4-(pyridine-2-yl)benzonitrile (32111-34-5) + rac-(T-4)-chloro(η5-pentamethylcyclopentadienyl)(2-phenylene-κC(1'),pyridine-κN)rhodium(III) (945491-50-9)

Guidance literature:

With sodium acetate; acetic acid; In methanol; at 40 ℃; under 760.051 Torr; Equilibrium constant; Inert atmosphere;

DOI:10.1021/acs.joc.9b01716

Reference yield:

2-phenylpyridine (1008-89-5) + Cp*RhCl(2-(4-methoxyphenyl)pyridine) (1552265-73-2) → 4-(2-pyridinyl)anisole (5957-90-4) + rac-(T-4)-chloro(η5-pentamethylcyclopentadienyl)(2-phenylene-κC(1'),pyridine-κN)rhodium(III) (945491-50-9)

Guidance literature:

With sodium acetate; acetic acid; In d⁽⁴⁾-methanol; at 40 ℃; under 760.051 Torr; Equilibrium constant; Inert atmosphere;

DOI:10.1021/acs.joc.9b01716

Reference yield:

2-phenylpyridine (1008-89-5) + C22H22ClF3NRh → rac-(T-4)-chloro(η5-pentamethylcyclopentadienyl)(2-phenylene-κC(1'),pyridine-κN)rhodium(III) (945491-50-9) + 2-(4-trifluoromethylphenyl)pyridine (203065-88-7)

Guidance literature:

With sodium acetate; acetic acid; In d⁽⁴⁾-methanol; at 40 ℃; under 760.051 Torr; Equilibrium constant; Inert atmosphere;

DOI:10.1021/acs.joc.9b01716

upstream raw materials:

2-phenylpyridine

Cp*RhCl(2-(4-methoxyphenyl)pyridine)

Downstream raw materials:

((C₅(CH₃)5)Rh(NC₅H₄C₆H₄CHC(C₆H₅)CCHC₆H₅))⁽¹⁺⁾*Cl^(1-)=((C₅(CH₃)5)Rh(NC₅H₄C₆H₄CHC(C₆H₅)CCHC₆H₅))Cl

((C₅(CH₃)5)RhCl(NC₅H₄C₆H₄C(COOC₂H₅)CC₆H₅))

((C₅(CH₃)5)RhCl(NC₅H₄C₆H₄C(C₆H₅)CCOOC₂H₅))

2-(2-(5-methylthiophen-2-yl)phenyl)pyridine

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 945491-50-9 rac-(T-4)-chloro(η5-pentamethylcyclopentadienyl)(2-phenylene-κC(1'),pyridine-κN)rhodium(III)

Send

Send

Metric Ton KG G Pound L ML

Send

Send