C₃₆H₄₇F₃O₃Si₂

Base Information

• Chemical Name: C₃₆H₄₇F₃O₃Si₂
• CAS No.: 1601462-42-3
• Molecular Formula: C₃₆H₄₇F₃O₃Si₂
• Molecular Weight: 640.934
• Mol file: 1601462-42-3.mol

Synonyms:C₃₆H₄₇F₃O₃Si₂

Chemical Property of C₃₆H₄₇F₃O₃Si₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₆H₄₇F₃O₃Si₂

There total 7 articles about C₃₆H₄₇F₃O₃Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

C18H29F3O7P2 (1601462-26-3) + p-[(tert-butyldimethylsilyl)oxy]benzaldehyde (120743-99-9) → C36H47F3O3Si2 (1601462-42-3)

Guidance literature:

C₁₈H₂₉F₃O₇P₂; With potassium tert-butylate; In tetrahydrofuran; at -10 ℃; for 0.333333h; Inert atmosphere;

p-[(tert-butyldimethylsilyl)oxy]benzaldehyde; In tetrahydrofuran; at 20 ℃; for 16h; Inert atmosphere;

DOI:10.1016/j.bmc.2014.02.054

Reference yield:

2,5-Dimethylaniline (95-78-3) → C36H47F3O3Si2 (1601462-42-3)

Guidance literature:

Multi-step reaction with 5 steps

1.1: tetrafluoroboric acid; sodium nitrite / water / 0 - 20 °C / Inert atmosphere

2.1: 18 h / Reflux; Inert atmosphere

3.1: dibenzoyl peroxide; N-Bromosuccinimide / tetrachloromethane / 16 h / Inert atmosphere; Reflux

4.1: 16 h / 150 °C / Inert atmosphere

5.1: potassium tert-butylate / tetrahydrofuran / 0.33 h / -10 °C / Inert atmosphere

5.2: 16 h / 20 °C / Inert atmosphere

With N-Bromosuccinimide; tetrafluoroboric acid; potassium tert-butylate; sodium nitrite; dibenzoyl peroxide; In tetrahydrofuran; tetrachloromethane; water; 4.1: |Arbuzov Reaction / 5.2: |Horner-Wadsworth-Emmons Olefination;

DOI:10.1016/j.bmc.2014.02.054

Reference yield:

2,5-dimethylbenzenediazonium tetrafluoroborate → C36H47F3O3Si2 (1601462-42-3)

Guidance literature:

Multi-step reaction with 4 steps

1.1: 18 h / Reflux; Inert atmosphere

2.1: dibenzoyl peroxide; N-Bromosuccinimide / tetrachloromethane / 16 h / Inert atmosphere; Reflux

3.1: 16 h / 150 °C / Inert atmosphere

4.1: potassium tert-butylate / tetrahydrofuran / 0.33 h / -10 °C / Inert atmosphere

4.2: 16 h / 20 °C / Inert atmosphere

With N-Bromosuccinimide; potassium tert-butylate; dibenzoyl peroxide; In tetrahydrofuran; tetrachloromethane; 3.1: |Arbuzov Reaction / 4.2: |Horner-Wadsworth-Emmons Olefination;

DOI:10.1016/j.bmc.2014.02.054

upstream raw materials:

C₁₀H₉Br₂F₃O

2,5-Dimethylaniline

4-hydroxy-benzaldehyde

tert-butyldimethylsilyl chloride

Downstream raw materials:

(E,E)-1-(2,2,2-trifluoroethoxy)-2,5-bis(4-hydroxy)styrylbenzene