2,3,7,8,12,13,17,18-octakis(benzylthio)porphyrazine

Base Information

• Chemical Name: 2,3,7,8,12,13,17,18-octakis(benzylthio)porphyrazine
• CAS No.: 129491-60-7
• Molecular Formula: C₇₂H₅₈N₈S₈
• Molecular Weight: 1291.83
• Mol file: 129491-60-7.mol

Synonyms:2,3,7,8,12,13,17,18-octakis(benzylthio)porphyrazine

Chemical Property of 2,3,7,8,12,13,17,18-octakis(benzylthio)porphyrazine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,7,8,12,13,17,18-octakis(benzylthio)porphyrazine

There total 5 articles about 2,3,7,8,12,13,17,18-octakis(benzylthio)porphyrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[Mg(C4N2(SCH2C6H5)2)4] → 2,3,7,8,12,13,17,18-octakis(benzylthio)porphyrazine (129491-60-7)

Guidance literature:

Reference yield: 81.0%

C72H56MgN8S8 → 2,3,7,8,12,13,17,18-octakis(benzylthio)porphyrazine (129491-60-7)

Guidance literature:

With sulfuric acid; trifluoroacetic acid; at 20 ℃; for 0.0166667h;

DOI:10.1016/j.tetlet.2015.02.033

Reference yield:

benzyl bromide (100-39-0) → 2,3,7,8,12,13,17,18-octakis(benzylthio)porphyrazine (129491-60-7)

Guidance literature:

Multi-step reaction with 2 steps

1: methanol / 0 °C

2: 1.) Mg(OPr)2, 2.) CF₃COOH / 1.) PrOH, 100 deg C, 12 h, 2.) 25 deg C, 16 h

With magnesium n-propylate; trifluoroacetic acid; In methanol;

DOI:10.1021/ja00176a059

upstream raw materials:

2,3-bis(benzylsulfanyl)maleonitrile

1-imino-4,7-bis(1-methylethoxy)-1H-isoindolin-3-amine

benzyl bromide

Downstream raw materials:

{2,3,7,8,12,13,17,18-octakis(benzylthio)porphyrazinato}copper(II)