3-(hexadecylsulfonyl)-2-<(hexadecylsulfonyl)methyl>propyl 3,6-di-O-benzoyl-2-deoxy-β-D-arabino-hexopyranoside

Base Information

Chemical Name:3-(hexadecylsulfonyl)-2-<(hexadecylsulfonyl)methyl>propyl 3,6-di-O-benzoyl-2-deoxy-β-D-arabino-hexopyranoside
CAS No.:176165-39-2
Molecular Formula:C₅₆H₉₂O₁₁S₂
Molecular Weight:1005.47
Hs Code.:

Synonyms:3-(hexadecylsulfonyl)-2-<(hexadecylsulfonyl)methyl>propyl 3,6-di-O-benzoyl-2-deoxy-β-D-arabino-hexopyranoside

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Chemical Property of 3-(hexadecylsulfonyl)-2-<(hexadecylsulfonyl)methyl>propyl 3,6-di-O-benzoyl-2-deoxy-β-D-arabino-hexopyranoside

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Technology Process of 3-(hexadecylsulfonyl)-2-<(hexadecylsulfonyl)methyl>propyl 3,6-di-O-benzoyl-2-deoxy-β-D-arabino-hexopyranoside

There total 4 articles about 3-(hexadecylsulfonyl)-2-<(hexadecylsulfonyl)methyl>propyl 3,6-di-O-benzoyl-2-deoxy-β-D-arabino-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 98-88-4
benzoyl chloride

: 176165-38-1
3-(hexadecylsulfonyl)-2-<(hexadecylsulfonyl)methyl>propyl 2-deoxy-β-D-arabino-hexopyranoside

: 176165-39-2
3-(hexadecylsulfonyl)-2-<(hexadecylsulfonyl)methyl>propyl 3,6-di-O-benzoyl-2-deoxy-β-D-arabino-hexopyranoside

Guidance literature:: 3-(hexadecylsulfonyl)-2-<(hexadecylsulfonyl)methyl>propyl 2-deoxy-β-D-arabino-hexopyranoside; With di(n-butyl)tin oxide; In toluene; benzene; Heating;

benzoyl chloride; In toluene; at 90 ℃; for 0.333333h;
DOI:10.1016/S0040-4020(02)00661-0

Reference yield:

: 13322-90-2
3,4,6-tri-O-benzoyl-D-glucal

: 176165-39-2
3-(hexadecylsulfonyl)-2-<(hexadecylsulfonyl)methyl>propyl 3,6-di-O-benzoyl-2-deoxy-β-D-arabino-hexopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: HCl / toluene / 0.67 h

2: 48 percent / silver silicate / CH₂Cl₂ / 0 deg C, 0.5h; rt, 30 h

3: MeONa / methanol / 5 h / Ambient temperature

4: 1.) Bu₂SnO / 1.) toluene, benzene, reflux, 2.) 3 min

With hydrogenchloride; silver silicate; sodium methylate; di(n-butyl)tin oxide; In methanol; dichloromethane; toluene;
DOI:10.1021/jo951914k

Reference yield:

: 3,4,6-tri-O-benzoyl-2-deoxy-α-D-arabino-hexopyranosyl chloride

: 176165-39-2
3-(hexadecylsulfonyl)-2-<(hexadecylsulfonyl)methyl>propyl 3,6-di-O-benzoyl-2-deoxy-β-D-arabino-hexopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 48 percent / silver silicate / CH₂Cl₂ / 0 deg C, 0.5h; rt, 30 h

2: MeONa / methanol / 5 h / Ambient temperature

3: 1.) Bu₂SnO / 1.) toluene, benzene, reflux, 2.) 3 min

With silver silicate; sodium methylate; di(n-butyl)tin oxide; In methanol; dichloromethane;
DOI:10.1021/jo951914k