methyl (E)-4-hydroxy-2-methoxymethoxy-6-methyl-3<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

Base Information

Chemical Name:methyl (E)-4-hydroxy-2-methoxymethoxy-6-methyl-3<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate
CAS No.:118608-04-1
Molecular Formula:C₂₆H₃₄O₆
Molecular Weight:442.552
Hs Code.:

Synonyms:methyl (E)-4-hydroxy-2-methoxymethoxy-6-methyl-3<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

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Chemical Property of methyl (E)-4-hydroxy-2-methoxymethoxy-6-methyl-3<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

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Technology Process of methyl (E)-4-hydroxy-2-methoxymethoxy-6-methyl-3<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

There total 18 articles about methyl (E)-4-hydroxy-2-methoxymethoxy-6-methyl-3<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 118608-03-0
methyl (E)-2,4-di(methoxymethoxy)-6-methyl-3-<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

: 118608-04-1
methyl (E)-4-hydroxy-2-methoxymethoxy-6-methyl-3<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

Guidance literature:: With hydrogenchloride; In methanol;
DOI:10.1016/S0040-4020(01)85090-0

Reference yield:

: 27065-51-6
2-(diethoxymethyl)-4-bromofuran

: 118608-04-1
methyl (E)-4-hydroxy-2-methoxymethoxy-6-methyl-3<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: 47 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / Ambient temperature

2: 78 percent / 1.)BuLi / 1.) THF, -78 deg C to 0 deg C, 20 min, 2.) THF, -78 deg C, 30 min, then 0 deg C, 30 min

3: 74 percent / HCl / methanol

With hydrogenchloride; n-butyllithium; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide;
DOI:10.1016/S0040-4020(01)85090-0

Reference yield:

: 1071-73-4
5-Hydroxy-2-pentanone

: 118608-04-1
methyl (E)-4-hydroxy-2-methoxymethoxy-6-methyl-3<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

Guidance literature:: Multi-step reaction with 12 steps

1: 85 percent / imidazole / dimethylformamide / 24 h / 70 °C

2: 17.25 g / NaH / tetrahydrofuran; hexane; diethyl ether / 40 h / Ambient temperature

3: 96 percent / DIBAL / CH₂Cl₂ / -78 deg C, 1 h, then 0 deg C

4: CBr₄, Ph₃P / CH₂Cl₂ / 1 h / -78 °C

5: 3.10 g / toluene / 12 h / Heating

6: 66 percent / NaH / CH₂Cl₂ / 1 h / Ambient temperature

7: 100 percent / tetrabutylammonium fluoride / tetrahydrofuran / 2 h

8: 100 percent / triethylamine / CH₂Cl₂ / 0.5 h / 0 °C

9: 94 percent / NaI / acetone / 4 h / 50 °C

10: 47 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / Ambient temperature

11: 78 percent / 1.)BuLi / 1.) THF, -78 deg C to 0 deg C, 20 min, 2.) THF, -78 deg C, 30 min, then 0 deg C, 30 min

12: 74 percent / HCl / methanol

With 1H-imidazole; hydrogenchloride; n-butyllithium; carbon tetrabromide; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; triethylamine; triphenylphosphine; sodium iodide; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; hexane; dichloromethane; N,N-dimethyl-formamide; acetone; toluene;
DOI:10.1016/S0040-4020(01)85090-0