[(4-Methylphenyl)methyl]boronic acid

Base Information

Chemical Name:[(4-Methylphenyl)methyl]boronic acid
CAS No.:21983-00-6
Molecular Formula:C₈H₁₁BO₂
Molecular Weight:149.985
Hs Code.:
DSSTox Substance ID:DTXSID00598336
Nikkaji Number:J1.951.757H
Wikidata:Q82494085

Synonyms:(4-methylbenzyl)boronic acid;21983-00-6;4-methylbenzylboronic acid;[(4-Methylphenyl)methyl]boronic acid;(4-methylbenzyl)boronicacid;SCHEMBL1356833;DTXSID00598336;AKOS013012886;F20813;EN300-1253035

Suppliers and Price of [(4-Methylphenyl)methyl]boronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
(4-Methylbenzyl)boronicacid 97%
1g
$ 416.00

Crysdot
(4-Methylbenzyl)boronicacid 97%
250mg
$ 166.00

Total 3 raw suppliers

Chemical Property of [(4-Methylphenyl)methyl]boronic acid

Chemical Property:

Boiling Point:310.9±45.0 °C(Predicted)
Density:1.079±0.06 g/cm3(Predicted)
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:150.0852098
Heavy Atom Count:11
Complexity:109

Purity/Quality:

99% ^*data from raw suppliers

(4-Methylbenzyl)boronicacid 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:B(CC1=CC=C(C=C1)C)(O)O

Technology Process of [(4-Methylphenyl)methyl]boronic acid

There total 2 articles about [(4-Methylphenyl)methyl]boronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 104-81-4
4-Methylbenzyl bromide

: 21983-00-6
4-methylbenzylboronic acid

Guidance literature:: 4-Methylbenzyl bromide; With magnesium; triethylamine; benzo[1,3,2]dioxaborole; In tetrahydrofuran; at 65 ℃; for 40h;

With hydrogenchloride; In water; pH=1;

Reference yield: 45.0%

: 104-82-5
4-Methylbenzyl chloride

: 21983-00-6
4-methylbenzylboronic acid

Guidance literature:: With Triisopropyl borate; bis(trifluoromethane)sulfonimide lithium; In N,N-dimethyl-formamide; at 20 ℃; Electrochemical reaction;
DOI:10.1016/j.tetlet.2004.09.005

Reference yield: 98.0%

: 21983-00-6
4-methylbenzylboronic acid

: C₁₆H₁₈O₂S

: tert-butyl (R)-3-(benzo[b]thiophen-2-yl)-2-(4-methylbenzyl)propanoate

Guidance literature:: 4-methylbenzylboronic acid; C₁₆H₁₈O₂S; With [RhCl(cis-cyclooctene)2]2; C₂₂H₂₂; In toluene; at 20 ℃; for 0.5h; Inert atmosphere;

With water; potassium hydroxide; In toluene; at 20 ℃; for 12h; enantioselective reaction; Inert atmosphere;
DOI:10.1039/d0ob00616e