(R)-glycidyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzoyl-β-D-galactopyranoside

Base Information

Chemical Name:(R)-glycidyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzoyl-β-D-galactopyranoside
CAS No.:459432-48-5
Molecular Formula:C₆₄H₆₂O₁₅
Molecular Weight:1071.19
Hs Code.:

Synonyms:(R)-glycidyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzoyl-β-D-galactopyranoside

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Chemical Property of (R)-glycidyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzoyl-β-D-galactopyranoside

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Technology Process of (R)-glycidyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzoyl-β-D-galactopyranoside

There total 8 articles about (R)-glycidyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzoyl-β-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 60456-23-7
(S)-oxiranemethanol

: 213743-12-5
ethyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzoyl-1-thio-β-D-galactopyranoside

: 459432-48-5
(R)-glycidyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzoyl-β-D-galactopyranoside

Guidance literature:: With 2,3,5-trimethyl-pyridine; dimethyl-(methylthio)-sulphonium trifluoromethanesulphonate; In dichloromethane; for 1.5h;
DOI:10.1016/S0040-4020(02)00473-8

Reference yield:

: 98-88-4
benzoyl chloride

: 459432-48-5
(R)-glycidyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzoyl-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 89 percent / pyridine / 1 h

2: TFA / CH₂Cl₂; ethane-1,2-diol / 1 h

3: 909 mg / pyridine / 0.5 h

4: 71 percent / 4 Angstroem molecular sieves; DMTST / diethyl ether / 3 h

5: 86 percent / collidine; dimethyl(methylthio)sulfonium trifluoromethanesulfonate / CH₂Cl₂ / 1.5 h

With pyridine; 2,3,5-trimethyl-pyridine; 4 A molecular sieve; dimethyl-(methylthio)-sulphonium trifluoromethanesulphonate; trifluoroacetic acid; In diethyl ether; dichloromethane; ethylene glycol;
DOI:10.1016/S0040-4020(02)00473-8

Reference yield:

: 125411-99-6
ethyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside

: 459432-48-5
(R)-glycidyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzoyl-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 71 percent / 4 Angstroem molecular sieves; DMTST / diethyl ether / 3 h

2: 86 percent / collidine; dimethyl(methylthio)sulfonium trifluoromethanesulfonate / CH₂Cl₂ / 1.5 h

With 2,3,5-trimethyl-pyridine; 4 A molecular sieve; dimethyl-(methylthio)-sulphonium trifluoromethanesulphonate; In diethyl ether; dichloromethane;
DOI:10.1016/S0040-4020(02)00473-8