Diphenylmethylazide

Base Information

• Chemical Name: Diphenylmethylazide
• CAS No.: 6926-47-2
• Molecular Formula: C13H11 N3
• Molecular Weight: 209.25
• Hs Code.: 2929909090
• DSSTox Substance ID: DTXSID50219327
• Nikkaji Number: J466.066H
• Wikidata: Q83096253
• Mol file: 6926-47-2.mol

Synonyms:Diphenylmethyl azide;[azido(phenyl)methyl]benzene;6926-47-2;Benzene, 1,1'-(azidomethylene)bis-;Diphenylmethylazide;CCRIS 8031;SCHEMBL13983511;DTXSID50219327;EN300-5393407

Chemical Property of Diphenylmethylazide

Chemical Property:

• PSA: 49.75000
• LogP: 3.53906
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 209.095297364
• Heavy Atom Count: 16
• Complexity: 228

Purity/Quality:

DIPHENYLMETHYL AZIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(C2=CC=CC=C2)N=[N+]=[N-]

Technology Process of Diphenylmethylazide

There total 23 articles about Diphenylmethylazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,1-Diphenylmethanol (91-01-0) → diphenylmethylazide (6926-47-2)

Guidance literature:

With chloro-trimethyl-silane; trimethylsilylazide; In dichloromethane; at 20 ℃; for 0.666667h; Reagent/catalyst; Solvent;

DOI:10.1039/c4ra13238f

Reference yield: 99.0%

diphenylchloromethane (90-99-3) → diphenylmethylazide (6926-47-2)

Guidance literature:

With trimethylsilylazide; tetrabutyl ammonium fluoride; In tetrahydrofuran; at 40 ℃; for 120h;

DOI:10.1055/s-1995-3928

Reference yield: 99.0%

diphenylmethyl trimethylsilyl ether (14629-59-5) → diphenylmethylazide (6926-47-2)

Guidance literature:

With iron(III) chloride; trimethylsilylazide; In 1,2-dichloro-ethane; at 20 ℃; for 0.25h; Reagent/catalyst;

DOI:10.1002/chem.201202984

upstream raw materials:

1,1-Diphenylmethanol

diphenylchloromethane

Bromodiphenylmethane

2-(diphenylmethyloxy)tetrahydro-2H-pyran

Downstream raw materials:

N-benzhydryl-N-methyl-phosphoramidic acid dimethyl ester

1-(diphenylmethyl)-4-propyl-1H-1,2,3-triazole

1-(diphenylmethyl)-4-hexyl-1H-1,2,3-triazole

1-(diphenylmethyl)-4-heptyl-1H-1,2,3-triazole