[((2,6-iPr2C6H3)NC(Me)C(Me)N(2,6-iPr2C6H3))Pd(η3-allyl)]SbF6

Base Information

• Chemical Name: [((2,6-iPr2C6H3)NC(Me)C(Me)N(2,6-iPr2C6H3))Pd(η3-allyl)]SbF6
• CAS No.: 1219797-94-0
• Molecular Formula: C₃₁H₄₅N₂Pd*F₆Sb
• Molecular Weight: 787.872
• Mol file: 1219797-94-0.mol

Synonyms:[((2,6-iPr2C6H3)NC(Me)C(Me)N(2,6-iPr2C6H3))Pd(η3-allyl)]SbF6

Chemical Property of [((2,6-iPr2C6H3)NC(Me)C(Me)N(2,6-iPr2C6H3))Pd(η3-allyl)]SbF6

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [((2,6-iPr2C6H3)NC(Me)C(Me)N(2,6-iPr2C6H3))Pd(η3-allyl)]SbF6

There total 6 articles about [((2,6-iPr2C6H3)NC(Me)C(Me)N(2,6-iPr2C6H3))Pd(η3-allyl)]SbF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tert-butyl vinyl ether (926-02-3) + [((2,6-iPr2C6H3)NC(Me)C(Me)N(2,6-iPr2C6H3))Pd(Et2O)Me]SbF6 (181707-48-2) → [((2,6-iPr2C6H3)NC(Me)C(Me)N(2,6-iPr2C6H3))Pd(η3-allyl)]SbF6 (1219797-94-0)

Guidance literature:

In CD₂Cl₂; byproducts: (CH3)3COH; (inert atm.); addn. of vinyl ether deriv. to palladium compd. in CD2Cl2 at -196°C, warming to -78°C, shaking, warming to room temp.; NMR monitoring; Kinetics;

DOI:10.1021/ja100491y

Reference yield:

[((2,6-iPr2C6H3)NC(Me)C(Me)N(2,6-iPr2C6H3))Pd(Et2O)Me]SbF6 (181707-48-2) + triphenylsilyl vinyl ether (55619-67-5) → [((2,6-iPr2C6H3)NC(Me)C(Me)N(2,6-iPr2C6H3))Pd(η3-allyl)]SbF6 (1219797-94-0)

Guidance literature:

In CD₂Cl₂; byproducts: (C6H5)3SiOH; (inert atm.); addn. of vinyl ether deriv. to palladium compd. in CD2Cl2 at -196°C, warming to -78°C, shaking, warming to room temp.; NMR monitoring; Kinetics;

DOI:10.1021/ja100491y

Reference yield:

[((2,6-iPr2C6H3)NC(Me)C(Me)N(2,6-iPr2C6H3))Pd(Et2O)Me]SbF6 (181707-48-2) + dimethylphenylsilyl vinyl ether (56583-90-5) → [((2,6-iPr2C6H3)NC(Me)C(Me)N(2,6-iPr2C6H3))Pd(η3-allyl)]SbF6 (1219797-94-0)

Guidance literature:

In CD₂Cl₂; byproducts: (C6H5(CH3)2Si)2O, H2O; (inert atm.); addn. of vinyl ether deriv. to palladium compd. in CD2Cl2 at -196°C, warming to -78°C, shaking, warming to room temp.; NMR monitoring; Kinetics;

DOI:10.1021/ja100491y

upstream raw materials:

[((2,6-iPr₂C₆H₃)NC(Me)C(Me)N(2,6-iPr₂C₆H₃))Pd(Et₂O)Me]SbF₆

triphenylsilyl vinyl ether

trimethylsiloxyethene

dimethylphenylsilyl vinyl ether