56583-90-5Relevant academic research and scientific papers
Chemoselective ruthenium-catalyzed reduction of acid chlorides to aldehydes with dimethylphenylsilane
Gutsulyak, Dmitry V.,Nikonov, Georgii I.
, p. 607 - 611 (2012)
A variety of aromatic and alkyl acid chlorides can be selectively converted into aldehydes using dimethylphenyl silane (HSiMe2Ph) as the reducing reagent in the presence of the cationic ruthenium catalyst {Cp[(i-Pr)3P]Ru(NCMe)2}+ [PF6] -. The reactions proceed under very mild conditions and are tolerant to many functional groups. Copyright
METHOD FOR THE CATALYTIC REDUCTION OF ACID CHLORIDES AND IMIDOYL CHLORIDES
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Paragraph 0104, (2014/08/19)
The present application relates to methods for the catalytic reduction of acid chlorides and/or imidoyl chlorides. The methods comprise reacting the acid chloride or imidoyl chloride with a silane reducing agent in the presence of a catalyst such as [Cp(Pri3P)Ru(NCMe)2]+[PF6]?.
A new general route to acceptor-substituted vinyloxiranes via siloxyoxiranes - Novel promising synthetic building-blocks
Schaumann, Ernst,Tries, Frank
, p. 191 - 194 (2007/10/03)
Epoxidation of silyl enol ethers 2a,b with dimethyldioxirane yields siloxyoxiranes 3a,b. Anions 4a-d lead to nucleophilic ring-opening in the acetal position C-1 of 3 to give diols 5a-d. Monotosylation and cyclisation provide acceptor-substituted vinyloxiranes 6a-d.
