3{N(P(C₆H₅)3)2}⁽¹⁺⁾*FeIr₅(CO)15^(3-)={N(P(C₆H₅)3)2}3{FeIr₅(CO)15}

Base Information

Chemical Name:3{N(P(C₆H₅)3)2}⁽¹⁺⁾*FeIr₅(CO)15^(3-)={N(P(C₆H₅)3)2}3{FeIr₅(CO)15}
CAS No.:134681-82-6
Molecular Formula:C₁₅FeIr₅O₁₅*3C₃₆H₃₀NP₂
Molecular Weight:3052.87
Hs Code.:

3{N(P(C<sub>6</sub>H<sub>5</sub>)3)2}<sup>(1+)</sup>*FeIr<sub>5</sub>(CO)15<sup>(3-)</sup>={N(P(C<sub>6</sub>H<sub>5</sub>)3)2}3{FeIr<sub>5</sub>(CO)15}

Synonyms:3{N(P(C₆H₅)3)2}⁽¹⁺⁾*FeIr₅(CO)15^(3-)={N(P(C₆H₅)3)2}3{FeIr₅(CO)15}

Suppliers and Price of 3{N(P(C₆H₅)3)2}⁽¹⁺⁾*FeIr₅(CO)15^(3-)={N(P(C₆H₅)3)2}3{FeIr₅(CO)15}

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3{N(P(C₆H₅)3)2}⁽¹⁺⁾*FeIr₅(CO)15^(3-)={N(P(C₆H₅)3)2}3{FeIr₅(CO)15}

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3{N(P(C₆H₅)3)2}⁽¹⁺⁾*FeIr₅(CO)15^(3-)={N(P(C₆H₅)3)2}3{FeIr₅(CO)15}

There total 1 articles about 3{N(P(C₆H₅)3)2}⁽¹⁺⁾*FeIr₅(CO)15^(3-)={N(P(C₆H₅)3)2}3{FeIr₅(CO)15} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 56557-01-8
{bis(triphenylphosphine)nitrogen(1+)} tetracarbonyliridate

: 2{N(P(C₆H₅)3)2}⁽¹⁺⁾*FeIr₄^(2-)*15(CO)={N(P(C₆H₅)3)2}2{FeIr₄(CO)15}

: 134681-85-9
2{N(P(C₆H₅)3)2}⁽¹⁺⁾*{HFeIr₅(CO)15}^(2-)={N(P(C₆H₅)3)2}2{HFeIr₅(CO)15}

: 134681-82-6
3{N(P(C₆H₅)3)2}⁽¹⁺⁾*FeIr₅(CO)15^(3-)={N(P(C₆H₅)3)2}3{FeIr₅(CO)15}

Guidance literature:: In acetonitrile; under O2-free N2, Schlenk-tube technique; FeIr-cluster (prepd. from Ir4(CO)12 and Fe(CO)5) was extd. from the frit with CH3CN and Ir-compd. was added, soln. was refluxed for 5 h; solvent was evapd. in vac., oily residue was transformed into microcrystals by suspending in MeOH, soln. was decanted by syringe, ppt. was extd. twice with THF (removing of sol. compd.), the residue can be used without further purifn.;

Reference yield: 80.0%

: 134681-82-6
3{N(P(C₆H₅)3)2}⁽¹⁺⁾*FeIr₅(CO)15^(3-)={N(P(C₆H₅)3)2}3{FeIr₅(CO)15}

: 56-93-9
benzyltrimethylammonium chloride

: 134681-86-0
3{N(CH₃)3(CH₂(C₆H₅))}⁽¹⁺⁾*FeIr₅(CO)15^(3-)={N(CH₃)3(CH₂(C₆H₅))}3{FeIr₅(CO)15}

Guidance literature:: With Na{BPh₄}; In acetone; byproducts: {N(PPh3)2}BPh4; under O2-free N2; FeIr-compd. in acetone was treated with stoich. amt. of Na(BPh4), pptd. insol. (N(PPh3)2)BPh4 was filtered off, solvent dried in vac., residue was dissolved (MeOH) and treated with excess of (NMe3(CH2Ph))Cl, pptn.;

Reference yield: 61.0%

: 134681-82-6
3{N(P(C₆H₅)3)2}⁽¹⁺⁾*FeIr₅(CO)15^(3-)={N(P(C₆H₅)3)2}3{FeIr₅(CO)15}

: 134681-88-2
{N(P(C₆H₅)3)2}⁽¹⁺⁾*{FeIr₅(CO)16}^(1-)={N(P(C₆H₅)3)2}{FeIr₅(CO)16}

Guidance literature:: With H₂SO₄; In tetrahydrofuran; under O2-free N2, Schlenk-tube technique; the FeIr-compd. was suspended in THF and concd. H2SO4 was slowly added, the complete conversion was checked by IR-spectroscopy, the mixt. was stirred at room temp. for 2 h; the solvent was removed in vac., the residue was dissolved in MeOH, powder was collected by filtn., washed with 2-propanol and crystd. from CH2Cl2/cyclohexane, elem. anal.;