Tricyclohexylphosphine carbon disulfide

Base Information

Chemical Name:Tricyclohexylphosphine carbon disulfide
CAS No.:2636-88-6
Molecular Formula:C19H33PS2
Molecular Weight:356.577
Hs Code.:2930909090
DSSTox Substance ID:DTXSID00883875
Mol file:2636-88-6.mol

Synonyms:2636-88-6;Tricyclohexylphosphine carbon disulfide;SCHEMBL2998464;C18H33P.CS2;DTXSID00883875;C18-H33-P.C-S2;tricyclohexyl phosphine carbon disulfide;Tricyclohexylphosphin-Schwefelkohlenstoff-Addukt

Suppliers and Price of Tricyclohexylphosphine carbon disulfide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 1 raw suppliers

Chemical Property of Tricyclohexylphosphine carbon disulfide

Chemical Property:

Vapor Pressure:9.7E-06mmHg at 25°C
Boiling Point:383.4°Cat760mmHg
Flash Point:195.6°C
PSA：77.77000
Density:g/cm³
LogP:7.48450
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:356.17613040
Heavy Atom Count:22
Complexity:220

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C(=S)=S

Technology Process of Tricyclohexylphosphine carbon disulfide

There total 1 articles about Tricyclohexylphosphine carbon disulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 75-15-0,12122-00-8
carbon disulfide

: 542-18-7
cyclohexyl chloride

: 2636-88-6
tricyclohexyl-phosphine; compound with carbon disulfidate

Guidance literature:: cyclohexyl chloride; With magnesium; ethylene dibromide; In diethyl ether; at 41 ℃; for 2h; Heating / reflux;

With phosphorus trichloride; In diethyl ether; tert-butyl methyl ether; at -17 - 20 ℃; Heating / reflux;

carbon disulfide; In diethyl ether; tert-butyl methyl ether; Product distribution / selectivity;

Reference yield: 91.0%

: 20816-12-0
osmium(VIII) oxide

: 2636-88-6
tricyclohexyl-phosphine; compound with carbon disulfidate

: OsO₂Cl₂(P(C₆H₁₁)3)2

Guidance literature:: With hydrogenchloride; In ethanol; benzene; The phosphorous compound suspended in degassed benzene is heated till the purple colour disappears. This warm solution is added to a solution of OsO4 and HCl in ethanol. stirring for 20 min.; washing with water, ethanol, ether, drying;

Reference yield: 85.0%

: trans-{PtH(C₆Cl₅)(PMe₃)2}

: 2923-28-6
silver trifluoromethanesulfonate

: 2636-88-6
tricyclohexyl-phosphine; compound with carbon disulfidate

: {(P(CH₃)3)2(C₆Cl₅)Pt(H)Ag(P(C₆H₁₁)3)}⁽¹⁺⁾*CF₃SO₃^(1-)={(P(CH₃)3)2(C₆Cl₅)Pt(H)Ag(P(C₆H₁₁)3)}(CF₃SO₃)

Guidance literature:: In diethyl ether; byproducts: CS2; refluxing PCy3*CS2 suspension in ethanol under N2, 15 min; evapn. to dryness; addn. of AgCF3SO3, Pt complex and Et2O; vigorously stirring suspension in the dark, 2h; filtration; elem. anal.;