cesium thiocyanate

Base Information

• Chemical Name: cesium thiocyanate
• CAS No.: 3879-01-4
• Molecular Formula: CCsNS
• Molecular Weight: 190.989
• Hs Code.: 2930909090
• Mol file: 3879-01-4.mol

Synonyms:Caesiumdichloriodid;Cesium dichloroiodide;Cesium thiocyanate;Cesium dichloroiodate;thiocyanic acid,cesium thiocyanate;dicesium oxalate;Caesiumrhodanid;caesium oxalate;Thiocyansaeure,Caesiumrhodanid;caesium(1+) dichloroiodanuide;Caesiumoxalat;caesium iodide dichloride;rubidium thiocyanate;

Chemical Property of cesium thiocyanate

Chemical Property:

• Vapor Pressure: 4.73mmHg at 25°C
• Melting Point: 207 °C
• Boiling Point: 146°C at 760 mmHg
• Flash Point: 42.1°C
• PSA: 23.79000
• Density: 2.933 g/cm3
• LogP: 0.01438

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cesium thiocyanate

There total 2 articles about cesium thiocyanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2Cs(1+)*Na(1+)*2Bi(3+)*7SCN(1-)*2F(1-)=Cs2Na{Bi2(SCN)7F2} → cesium sulfate + bismuth(III) sulfide + BiS0.86C3.06N4.16I1.75 + Cesium thiocyanate (3879-01-4) + cesium fluoride (13400-13-0)

Guidance literature:

With oxygen; In neat (no solvent); byproducts: NaCNS, NaF, Na2SO4; pyrolysis (260°C, porcelain crucible, air, heating rate 5°C/min); further gaseous products; not separated; thermal anal., X-ray diffraction;

DOI:10.1016/0040-6031(92)87054-E

Reference yield:

2Cs(1+)*Na(1+)*2Bi(3+)*6SCN(1-)*3F(1-)=Cs2Na{Bi2(SCN)6F3} → cesium sulfate + bismuth(III) sulfide + BiS0.26C2.2N3.16F2.75 + Cesium thiocyanate (3879-01-4) + cesium fluoride (13400-13-0)

Guidance literature:

With oxygen; In neat (no solvent); byproducts: NaSCN, Na2SO4, NaF; pyrolysis (260°C, porcelain crucible, air, heating rate 5°C/min); further gaseous products; not separated; thermal anal., X-ray diffraction;

DOI:10.1016/0040-6031(92)87054-E

Reference yield:

Cesium thiocyanate (3879-01-4) → cesium sulfate + carbon dioxide (124-38-9,18923-20-1) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3)

Guidance literature:

With air; In neat (no solvent); byproducts: N2; sample heating in air at 5 K/min up to 600°C; TG, XRD;

DOI:10.1016/s0040-6031(98)00391-8

Downstream raw materials:

carbon dioxide

sulfur dioxide

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