benzyldimethylselenonium fluorosulfonate

Base Information

• Chemical Name: benzyldimethylselenonium fluorosulfonate
• CAS No.: 75772-19-9
• Molecular Formula: C₉H₁₃Se*FO₃S
• Molecular Weight: 299.225
• Mol file: 75772-19-9.mol

Synonyms:benzyldimethylselenonium fluorosulfonate

Chemical Property of benzyldimethylselenonium fluorosulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyldimethylselenonium fluorosulfonate

There total 2 articles about benzyldimethylselenonium fluorosulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

Methyl fluorosulfonate (421-20-5) + benzyl methyl selenide (5925-78-0) → benzyldimethylselenonium fluorosulfonate (75772-19-9)

Guidance literature:

In tetrachloromethane; at 25 ℃; overnight;

DOI:10.1021/jo00345a011

Reference yield:

benzyl chloride (100-44-7) → benzyldimethylselenonium fluorosulfonate (75772-19-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) sodium borohydride / 1.) THF, water, 25 deg C, 2 h, 2.) overnight

2: 88 percent / CCl₄ / 25 °C / overnight

With sodium tetrahydroborate; In tetrachloromethane;

DOI:10.1021/jo00345a011

Reference yield: 43.0%

benzyldimethylselenonium fluorosulfonate (75772-19-9) → 2-methylbenzyl methyl selenide (75772-20-2)

Guidance literature:

With ammonia; sodium amide; at -78 ℃; for 1h;

DOI:10.1021/jo00345a011

upstream raw materials:

Methyl fluorosulfonate

benzyl methyl selenide

benzyl chloride

Downstream raw materials:

2-methylbenzyl methyl selenide