benzoic acid (1S,5S)-3-formyl-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enylmethyl ester

Base Information

Chemical Name:benzoic acid (1S,5S)-3-formyl-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enylmethyl ester
CAS No.:1187618-33-2
Molecular Formula:C₂₂H₃₀O₇
Molecular Weight:406.476
Hs Code.:

Synonyms:benzoic acid (1S,5S)-3-formyl-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enylmethyl ester

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Chemical Property of benzoic acid (1S,5S)-3-formyl-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enylmethyl ester

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Technology Process of benzoic acid (1S,5S)-3-formyl-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enylmethyl ester

There total 1 articles about benzoic acid (1S,5S)-3-formyl-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 1187618-32-1
benzoic acid (S)-3-hydroxymethyl-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enyl ester

: 1187618-33-2
benzoic acid (1S,5S)-3-formyl-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enylmethyl ester

Guidance literature:: With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1016/j.tet.2009.04.021

Reference yield: 53.0%

: 1187618-33-2
benzoic acid (1S,5S)-3-formyl-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enylmethyl ester

: 144067-43-6
((E)-5-Bromo-pent-1-enyl)-tributyl-stannane

: C₂₀H₃₅BrO₆

Guidance literature:: ((E)-5-Bromo-pent-1-enyl)-tributyl-stannane; With n-butyllithium; In tetrahydrofuran; hexanes; at -78 ℃; for 1h;

benzoic acid (1S,5S)-3-formyl-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enylmethyl ester; In tetrahydrofuran; hexanes; at -78 - 20 ℃; for 17.0333h;

With water; In tetrahydrofuran; hexanes; diethyl ether; at 20 ℃;
DOI:10.1016/j.tet.2009.04.021

Reference yield:

: 1187618-33-2
benzoic acid (1S,5S)-3-formyl-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enylmethyl ester

: 1187618-38-7
tert-butyl-[(E)-(S)-3-(4-methoxy-benzyloxy)-5-tributylstannanyl-pent-4-enyloxy]-dimethyl-silane

: (E)-(S)-6-(tert-butyl-dimethyl-silanyloxy)-1-((3S,5S)-5-hydroxymethyl-3,5-bis-methoxymethoxy-2,6,6-trimethyl-cyclohex-1-enyl)-4-(4-methoxy-benzyloxy)-hex-2-en-1-ol

: 1187618-39-8
(E)-(S)-6-(tert-butyl-dimethyl-silanyloxy)-1-((3S,5S)-5-hydroxymethyl-3,5-bis-methoxymethoxy-2,6,6-trimethyl-cyclohex-1-enyl)-4-(4-methoxy-benzyloxy)-hex-2-en-1-ol

Guidance literature:: tert-butyl-[(E)-(S)-3-(4-methoxy-benzyloxy)-5-tributylstannanyl-pent-4-enyloxy]-dimethyl-silane; With n-butyllithium; In tetrahydrofuran; hexanes; at -78 ℃; for 1h;

benzoic acid (1S,5S)-3-formyl-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enylmethyl ester; In tetrahydrofuran; hexanes; at -78 - 20 ℃; for 17.0333h;

With water; In tetrahydrofuran; hexanes; diethyl ether; at 20 ℃;
DOI:10.1016/j.tet.2009.04.021