trans-(2,4,6-trimethylphenyl)(N(C₆H₅)C(O)CH(C₆H₅)2)bis(trimethylphosphine)nickel(II)

Base Information

• Chemical Name: trans-(2,4,6-trimethylphenyl)(N(C₆H₅)C(O)CH(C₆H₅)2)bis(trimethylphosphine)nickel(II)
• CAS No.: 170957-84-3
• Molecular Formula: C₃₅H₄₅NNiOP₂
• Molecular Weight: 616.386

Synonyms:trans-(2,4,6-trimethylphenyl)(N(C₆H₅)C(O)CH(C₆H₅)2)bis(trimethylphosphine)nickel(II)

Chemical Property of trans-(2,4,6-trimethylphenyl)(N(C₆H₅)C(O)CH(C₆H₅)2)bis(trimethylphosphine)nickel(II)

Chemical Property:

Purity/Quality:

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Technology Process of trans-(2,4,6-trimethylphenyl)(N(C₆H₅)C(O)CH(C₆H₅)2)bis(trimethylphosphine)nickel(II)

There total 3 articles about trans-(2,4,6-trimethylphenyl)(N(C₆H₅)C(O)CH(C₆H₅)2)bis(trimethylphosphine)nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

trans-phenylamido(2,4,6-trimethylphenyl)bis(trimethylphosphine)nickel(II) (163362-39-8) + diphenyl ketene (525-06-4) → trans-(2,4,6-trimethylphenyl)(N(C6H5)C(O)CH(C6H5)2)bis(trimethylphosphine)nickel(II) (170957-84-3)

Guidance literature:

In pentane; Ar-atmosphere; addn. of 1 equiv. ketene to Ni-complex, stirring for 2 h; crystn. on cooling to -10°C; elem. anal.;

DOI:10.1021/ic00125a035

Reference yield:

potassium anilide (19642-99-0) → trans-(2,4,6-trimethylphenyl)(N(C6H5)C(O)CH(C6H5)2)bis(trimethylphosphine)nickel(II) (170957-84-3)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: pentane

In tetrahydrofuran; pentane;

DOI:10.1021/ic00125a035

Reference yield:

trans-{Ni(2,4,6-C6H2Me3)Br(PMe3)2} → trans-(2,4,6-trimethylphenyl)(N(C6H5)C(O)CH(C6H5)2)bis(trimethylphosphine)nickel(II) (170957-84-3)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: pentane

In tetrahydrofuran; pentane;

DOI:10.1021/ic00125a035

upstream raw materials:

trans-phenylamido(2,4,6-trimethylphenyl)bis(trimethylphosphine)nickel(II)

diphenyl ketene

potassium anilide

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