NiCl₂(3,6,9,12,15,18-hexaaza-1,2,10,11-tetraphenyl-2,9,11,18-tetraenecyclododecane)

Base Information

• Chemical Name: NiCl₂(3,6,9,12,15,18-hexaaza-1,2,10,11-tetraphenyl-2,9,11,18-tetraenecyclododecane)
• CAS No.: 227948-92-7
• Molecular Formula: C₃₆H₃₈Cl₂N₆Ni
• Molecular Weight: 684.334
• Mol file: 227948-92-7.mol

Synonyms:NiCl₂(3,6,9,12,15,18-hexaaza-1,2,10,11-tetraphenyl-2,9,11,18-tetraenecyclododecane)

Chemical Property of NiCl₂(3,6,9,12,15,18-hexaaza-1,2,10,11-tetraphenyl-2,9,11,18-tetraenecyclododecane)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of NiCl₂(3,6,9,12,15,18-hexaaza-1,2,10,11-tetraphenyl-2,9,11,18-tetraenecyclododecane)

There total 1 articles about NiCl₂(3,6,9,12,15,18-hexaaza-1,2,10,11-tetraphenyl-2,9,11,18-tetraenecyclododecane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

nickel(II) dichloride hydrate + 3-azapentane-1,5-diamine (111-40-0,98824-35-2) + benzil (134-81-6) → NiCl2(3,6,9,12,15,18-hexaaza-1,2,10,11-tetraphenyl-2,9,11,18-tetraenecyclododecane) (227948-92-7)

Guidance literature:

In ethanol; to hot soln. of benzil in EtOH neat diethylenetriamine added with stirring; soln. of metal dichloride in EtOH added dropwise over 30 min; mixt. was refluxed on water bath for about 5 hs; decanted; washed (EtOH, Et2O); dried (vac., CaCl2); elem. anal.;

DOI:10.1016/j.saa.2006.11.026

Reference yield:

NiCl2(3,6,9,12,15,18-hexaaza-1,2,10,11-tetraphenyl-2,9,11,18-tetraenecyclododecane) (227948-92-7) → nickel (7440-02-0)

Guidance literature:

In neat (no solvent); heated in N2 atm. with heating rate of 10.degree,C/min to 600°C;

DOI:10.1016/j.saa.2006.11.026

upstream raw materials:

3-azapentane-1,5-diamine

benzil

Downstream raw materials:

nickel