<(2Z,4E)-5-<(R)-4-hydroxy-2,6,6-trimethylcyclohex-1-enyl>-3-methylpenta-2,4-dienyl>triphenylphosphonium chloride

Base Information

Chemical Name:<(2Z,4E)-5-<(R)-4-hydroxy-2,6,6-trimethylcyclohex-1-enyl>-3-methylpenta-2,4-dienyl>triphenylphosphonium chloride
CAS No.:130696-70-7
Molecular Formula:C₃₃H₃₈OP*Cl
Molecular Weight:517.091
Hs Code.:

Synonyms:<(2Z,4E)-5-<(R)-4-hydroxy-2,6,6-trimethylcyclohex-1-enyl>-3-methylpenta-2,4-dienyl>triphenylphosphonium chloride

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of <(2Z,4E)-5-<(R)-4-hydroxy-2,6,6-trimethylcyclohex-1-enyl>-3-methylpenta-2,4-dienyl>triphenylphosphonium chloride

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Technology Process of <(2Z,4E)-5-<(R)-4-hydroxy-2,6,6-trimethylcyclohex-1-enyl>-3-methylpenta-2,4-dienyl>triphenylphosphonium chloride

There total 10 articles about <(2Z,4E)-5-<(R)-4-hydroxy-2,6,6-trimethylcyclohex-1-enyl>-3-methylpenta-2,4-dienyl>triphenylphosphonium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.3%

: 91739-51-4
<(2Z,4Z)-5-<(R)-4-hydroxy-2,6,6-trimethylcyclohex-1-enyl>-3-methylpenta-2,4-dienyl>triphenylphosphonium chloride

: 130696-70-7
<(2Z,4E)-5-<(R)-4-hydroxy-2,6,6-trimethylcyclohex-1-enyl>-3-methylpenta-2,4-dienyl>triphenylphosphonium chloride

Guidance literature:: With palladium diacetate; In methanol; at 65 ℃; for 4h;
DOI:10.1002/hlca.19910740507

Reference yield:

: 15647-89-9
triphenylphosphine hydrochloride

: (1-E)-1-<(4R)-4-hydroxy-2,6,6-trimethylcyclohex-1-enyl>-3-methyl-1,4-pentadien-3-ol

: 130696-70-7
<(2Z,4E)-5-<(R)-4-hydroxy-2,6,6-trimethylcyclohex-1-enyl>-3-methylpenta-2,4-dienyl>triphenylphosphonium chloride

Guidance literature:: In methanol; at 0 - 20 ℃;

Reference yield:

: 91662-50-9
[(Z)-5-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-3-methyl-pent-2-en-4-ynyl]-triphenyl-phosphonium; chloride

: 130696-70-7
<(2Z,4E)-5-<(R)-4-hydroxy-2,6,6-trimethylcyclohex-1-enyl>-3-methylpenta-2,4-dienyl>triphenylphosphonium chloride

Guidance literature:: Multi-step reaction with 2 steps

1: 68.3 percent / 2,2'-(ethylenedithio)bis, H₂ / Raney-Ni / methanol / 11 h / 30 °C / 750.06 Torr

2: 86.3 percent / Pd(OAc)2 / methanol / 4 h / 65 °C

With palladium diacetate; 2,2'-ethane-1,2-diylbissulfanyl-bis-ethanol; hydrogen; nickel; In methanol;
DOI:10.1002/hlca.19910740507