[(N,N’-bis(2,6-diisopropylphenyl)formamidinate)₂Sm^II(tetrahydrofuran)₂]

Base Information

• Chemical Name: [(N,N’-bis(2,6-diisopropylphenyl)formamidinate)₂Sm^II(tetrahydrofuran)₂]
• CAS No.: 858656-55-0
• Molecular Formula: C₅₈H₈₆N₄O₂Sm
• Molecular Weight: 1021.71

Synonyms:[(N,N’-bis(2,6-diisopropylphenyl)formamidinate)₂Sm^II(tetrahydrofuran)₂]

Chemical Property of [(N,N’-bis(2,6-diisopropylphenyl)formamidinate)₂Sm^II(tetrahydrofuran)₂]

Chemical Property:

Purity/Quality:

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Technology Process of [(N,N’-bis(2,6-diisopropylphenyl)formamidinate)₂Sm^II(tetrahydrofuran)₂]

There total 8 articles about [(N,N’-bis(2,6-diisopropylphenyl)formamidinate)₂Sm^II(tetrahydrofuran)₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

samarium diiodide bis(tetrahydrofuran) (94138-28-0) + N,N'-di(2,6-diisopropylphenyl)formamidine (1176938-29-6,581776-24-1) → [(N,N’-bis(2,6-diisopropylphenyl)formamidinate)2SmII(tetrahydrofuran)2] (858656-55-0)

Guidance literature:

With potassium; In tetrahydrofuran; at 20 ℃; Reflux;

DOI:10.1039/c6cc07367k

Reference yield: 78.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + samarium diiodide (32248-43-4) + N,N'-di(2,6-diisopropylphenyl)formamidine (1176938-29-6,581776-24-1) → [(N,N’-bis(2,6-diisopropylphenyl)formamidinate)2SmII(tetrahydrofuran)2] (858656-55-0)

Guidance literature:

N,N'-di(2,6-diisopropylphenyl)formamidine; With potassium; In tetrahydrofuran; for 3h; Schlenk technique; Inert atmosphere; Reflux;

tetrahydrofuran; samarium diiodide; at 20 ℃; Schlenk technique; Inert atmosphere;

DOI:10.1021/ic502181g

Reference yield: 70.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + samarium diiodide(tetrahydrofuran)2 + Na[DippForm](THF)3 → [(N,N’-bis(2,6-diisopropylphenyl)formamidinate)2SmII(tetrahydrofuran)2] (858656-55-0) + [(CH(NC6H3(CH(CH3)2)2)2)2SmI2(C4H8O)](1-)*Na(1+)*5C4H8O=[(CH(NC6H3(CH(CH3)2)2)2)2SmI2(C4H8O)](Na(C4H8O)5)

Guidance literature:

In tetrahydrofuran; byproducts: NaI; a soln. of Na compd. added to a soln. of Sm compd. at 0°C, gradually warmed to room temp., stirred for 2 h; filtered, volatiles removed (vac.), extd. (toluene), cooled to -10°C overnight; elem. anal.;

DOI:10.1039/b501447f

upstream raw materials:

tetrahydrofuran

N,N'-di(2,6-diisopropylphenyl)formamidine

samarium

samarium diiodide

Downstream raw materials:

[(CH(NC₆H₃(CH(CH₃)2)2)2)2SmF(C₄H₈O)]

[Sm(N,N'-bis(2,6-diisopropylphenyl)formamidinate)2(N,N'-bis(mesityl)formamidinate)]*hexane

[Sm(N,N'-bis(2,6-diisopropylphenyl)formamidinate)2(CyNC(CH₂Ph)NCy)]

[Sm(N,N'-bis(2,6-diisopropylphenyl)formamidinate)2(N,N'-bis(cyclohexyl)formamidinate)]*C₆H₅Me

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