(η-Cp)Fe(CO){P(Me)2Ph}COMe

Base Information

• Chemical Name: (η-Cp)Fe(CO){P(Me)2Ph}COMe
• CAS No.: 32993-87-6
• Molecular Formula: C₁₆H₁₉FeO₂P
• Molecular Weight: 330.146
• Mol file: 32993-87-6.mol

Synonyms:(η-Cp)Fe(CO){P(Me)2Ph}COMe

Chemical Property of (η-Cp)Fe(CO){P(Me)2Ph}COMe

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η-Cp)Fe(CO){P(Me)2Ph}COMe

There total 2 articles about (η-Cp)Fe(CO){P(Me)2Ph}COMe which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

dicarbonyl(cyclopentadienyl)methyliron(II) + Dimethyl(phenyl)phosphine (672-66-2) → (η-Cp)Fe(CO){P(Me)2Ph}COMe (32993-87-6)

Guidance literature:

In toluene; under N2 atm. PPhMe2 was added to soln. (CpFe(CH3)(CO)2) in toluene and refluxed for 2 h; solvent was removed in vacuo, residue was purified by chromy. on silica;elem. anal.;

DOI:10.1016/j.jorganchem.2004.07.013

Reference yield:

(η-Cp)Fe{PMe2Ph}(CO)(Me) (117228-57-6) → (η-Cp)Fe(CO){P(Me)2Ph}COMe (32993-87-6)

Guidance literature:

With carbon monoxide; In acetonitrile; Electrochem. Process; carbonylation reaction in CH3CN (0.1 M tetrabutylammonium hexafluorophosphate) under 1 atm CO at 0°C using voltammetry (acetyl-ferrocene/ferrocenium couple); Kinetics;

Reference yield: 89.0%

(η-Cp)Fe(CO){P(Me)2Ph}COMe (32993-87-6) + tris(pentafluorophenyl)borate (1109-15-5) → [Fe(η-C5H5)(MeCOB(C6F5)3)(CO)(PPhMe2)] (827611-77-8)

Guidance literature:

In toluene; under N2 atm. soln. B(C6F5)3 in toluene was added dropwise at -78°C to soln. (CpFe(CH3CO)(CO)(PPhMe2)) in toluene and stirred for 1 h at -78°C, react. mixt. was allowed to warm to room temp. with stirring; solvent was removed; elem. anal.;

DOI:10.1016/j.jorganchem.2004.07.013

upstream raw materials:

(η-Cp)Fe{PMe2Ph}(CO)(Me)

Dimethyl(phenyl)phosphine

Downstream raw materials:

C₅H₅Fe(CO)P(CH₃)2(C₆H₅)CCH₂⁽¹⁺⁾*BF₄^(1-)

[Fe(η-C5H5)(MeCOB(C6F5)3)(CO)(PPhMe2)]