10-phenylseleno-2-pinene

Base Information

• Chemical Name: 10-phenylseleno-2-pinene
• CAS No.: 233751-73-0
• Molecular Formula: C₁₆H₂₀Se
• Molecular Weight: 291.295
• Mol file: 233751-73-0.mol

Synonyms:10-phenylseleno-2-pinene

Chemical Property of 10-phenylseleno-2-pinene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10-phenylseleno-2-pinene

There total 4 articles about 10-phenylseleno-2-pinene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

Pinocarveylchlorid (253426-88-9) + sodium phenylselenide (23974-72-3) → 10-phenylseleno-2-pinene (233751-73-0)

Guidance literature:

In ethanol; at 0 - 50 ℃; for 2h; Inert atmosphere;

DOI:10.1016/j.tet.2009.10.005

Reference yield:

N-phenylselenenyl succinimide (68395-72-2) + beta-pinene (18172-67-3,19902-08-0,25719-60-2) → 10-phenylseleno-2-pinene (233751-73-0) + 10-phenylseleno-p-mentha-1,8-diene (350049-02-4)

Guidance literature:

With camphor-10-sulfonic acid; water; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1080/10426500902947682

Reference yield:

(1R)-Myrtenol (19894-97-4) → 10-phenylseleno-2-pinene (233751-73-0)

Guidance literature:

Multi-step reaction with 2 steps

1: PBr₃ / CH₂Cl₂

2: NaBH₄ / ethanol

With sodium tetrahydroborate; phosphorus tribromide; In ethanol; dichloromethane;

DOI:10.1002/(SICI)1099-0690(199905)1999:5<1011::AID-EJOC1011>3.0.CO;2-H

upstream raw materials:

diphenyl diselenide

(-)-myrtenyl bromide

(1R)-Myrtenol

Pinocarveylchlorid

Downstream raw materials:

6,6-dimethyl-2-methylene-bicyclo[3.1.1]heptan-3-ol

C₄₈H₇₉NO₇SSi₂

1-[2-(tert-Butyl-dimethyl-silanyloxy)-3-((1R,5S,6S,8R)-9,9-dimethyl-4,4-dioxo-4λ⁶-thia-tricyclo[6.1.1.0^2,6]dec-2-en-5-yl)-4,6-dimethoxy-phenyl]-3-methyl-butan-1-one

1-{2-(tert-Butyl-dimethyl-silanyloxy)-3-[(S)-((1R,3S,5R)-6,6-dimethyl-2-methylene-bicyclo[3.1.1]hept-3-yl)-hydroxy-methyl]-4,6-dimethoxy-phenyl}-3-methyl-butan-1-one