1-diazo-6-(2,2-diethyl-4-methyl-[1,3]dioxolan-4-yl)-9-(4-methoxy-benzyloxymethyl)-dec-9-ene-2,5-dione

Base Information

Chemical Name:1-diazo-6-(2,2-diethyl-4-methyl-[1,3]dioxolan-4-yl)-9-(4-methoxy-benzyloxymethyl)-dec-9-ene-2,5-dione
CAS No.:915708-11-1
Molecular Formula:C₂₇H₃₈N₂O₆
Molecular Weight:486.609
Hs Code.:

Synonyms:1-diazo-6-(2,2-diethyl-4-methyl-[1,3]dioxolan-4-yl)-9-(4-methoxy-benzyloxymethyl)-dec-9-ene-2,5-dione

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Chemical Property of 1-diazo-6-(2,2-diethyl-4-methyl-[1,3]dioxolan-4-yl)-9-(4-methoxy-benzyloxymethyl)-dec-9-ene-2,5-dione

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Technology Process of 1-diazo-6-(2,2-diethyl-4-methyl-[1,3]dioxolan-4-yl)-9-(4-methoxy-benzyloxymethyl)-dec-9-ene-2,5-dione

There total 4 articles about 1-diazo-6-(2,2-diethyl-4-methyl-[1,3]dioxolan-4-yl)-9-(4-methoxy-benzyloxymethyl)-dec-9-ene-2,5-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 915708-09-7
5-(2,2-diethyl-4-methyl-[1,3]dioxolan-4-yl)-8-(4-methoxy-benzyloxymethyl)-4-oxo-non-8-enal

: 915708-11-1
1-diazo-6-(2,2-diethyl-4-methyl-[1,3]dioxolan-4-yl)-9-(4-methoxy-benzyloxymethyl)-dec-9-ene-2,5-dione

Guidance literature:: Multi-step reaction with 3 steps

1: aq. NaClO₂; NaH₂PO₄; 2-methyl-2-butene / 2-methyl-propan-2-ol / 2 h / 20 °C

2: Et₃N / tetrahydrofuran / -20 - 0 °C

3: tetrahydrofuran; diethyl ether / 3 h / 20 °C

With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; triethylamine; In tetrahydrofuran; diethyl ether; tert-butyl alcohol; 1: Lindgren oxidation;
DOI:10.1002/anie.200602056

Reference yield:

: 915708-08-6
5-(2,2-diethyl-4-methyl-[1,3]dioxolan-4-yl)-8-(4-methoxy-benzyloxymethyl)-non-8-ene-1,4-diol

: 915708-11-1
1-diazo-6-(2,2-diethyl-4-methyl-[1,3]dioxolan-4-yl)-9-(4-methoxy-benzyloxymethyl)-dec-9-ene-2,5-dione

Guidance literature:: Multi-step reaction with 4 steps

1: (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 0.17 h / -78 °C

2: aq. NaClO₂; NaH₂PO₄; 2-methyl-2-butene / 2-methyl-propan-2-ol / 2 h / 20 °C

3: Et₃N / tetrahydrofuran / -20 - 0 °C

4: tetrahydrofuran; diethyl ether / 3 h / 20 °C

With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; oxalyl dichloride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; diethyl ether; dichloromethane; tert-butyl alcohol; 1: Swern oxidation / 2: Lindgren oxidation;
DOI:10.1002/anie.200602056

Reference yield:

: 915708-10-0
5-(2,2-diethyl-4-methyl-[1,3]dioxolan-4-yl)-8-(4-methoxy-benzyloxymethyl)-4-oxo-non-8-enoic acid

: 915708-11-1
1-diazo-6-(2,2-diethyl-4-methyl-[1,3]dioxolan-4-yl)-9-(4-methoxy-benzyloxymethyl)-dec-9-ene-2,5-dione

Guidance literature:: Multi-step reaction with 2 steps

1: Et₃N / tetrahydrofuran / -20 - 0 °C

2: tetrahydrofuran; diethyl ether / 3 h / 20 °C

With triethylamine; In tetrahydrofuran; diethyl ether;
DOI:10.1002/anie.200602056