methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

Base Information

Chemical Name:methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside
CAS No.:453525-05-8
Molecular Formula:C₆₂H₅₂O₁₇S
Molecular Weight:1101.15
Hs Code.:

Synonyms:methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

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Chemical Property of methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

Chemical Property:

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Technology Process of methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

There total 6 articles about methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 34234-44-1
methyl 2,3,4-tri-O-benzoylglucopyranoside

: 453524-99-7
2,3,4,6-tetra-O-benzoyl-5-deoxy-5-thio-α-D-glucopyranosyl trichloroacetimidate

: 453525-05-8
methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

: methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at -78 - -40 ℃;
DOI:10.1246/cl.2002.626

Reference yield:

: 453524-96-4
tetrahydropyran-2-yl 5-deoxy-5-thio-α-D-glucopyranoside

: 453525-05-8
methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 94 percent / pyridine / 1 h / 20 °C

2: 85 percent / p-TsOH / methanol / 7 h / 45 °C

3: 67 percent / 1,8-diazabicyclo[5.4.0]undec-7-ene / CH₂Cl₂ / 1 h / 0 °C

4: BF₃*OEt₂ / CH₂Cl₂ / 2 h / -78 °C

With pyridine; boron trifluoride diethyl etherate; toluene-4-sulfonic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; In methanol; dichloromethane;
DOI:10.1016/j.bmc.2005.05.028

Reference yield:

: 453525-11-6
tetrahydropyran-2-yl 2,3,4,6-tetra-O-acetyl-5-deoxy-5-thio-α-D-glucopyranoside

: 453525-05-8
methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 82 percent / NaOMe / methanol / 3.5 h / 20 °C

2: 94 percent / pyridine / 1 h / 20 °C

3: 85 percent / p-TsOH / methanol / 7 h / 45 °C

4: 67 percent / 1,8-diazabicyclo[5.4.0]undec-7-ene / CH₂Cl₂ / 1 h / 0 °C

5: BF₃*OEt₂ / CH₂Cl₂ / 2 h / -78 °C

With pyridine; boron trifluoride diethyl etherate; sodium methylate; toluene-4-sulfonic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; In methanol; dichloromethane;
DOI:10.1016/j.bmc.2005.05.028