453524-99-7Relevant articles and documents
Synthetic studies on oligosaccharides composed of 5-thioglucopyranose units
Morii, Yasuharu,Matsuda, Hiroko,Ohara, Keiichiro,Hashimoto, Masaru,Miyairi, Kazuo,Okuno, Toshikatsu
, p. 5113 - 5144 (2007/10/03)
Glycosylation reactions of 5-thioglucopyranosyl trichloroacetimidates bearing ethereal protective groups at the 2-O-position 14-15, and 37 proceed smoothly to give α-glycosides stereoselectively by using a catalytic amount of silyl triflate. This methodol
β-selective glycosylation of 5-thioglucopyranose derivatives; syntheses of β-(1 → 6) linked 5′-thioglucopyranosyl disaccharides
Ohara, Keiichiro,Matsuda, Hiroko,Hashimoto, Masaru,Miyairi, Kazuo,Okuno, Toshikatsu
, p. 626 - 627 (2007/10/03)
β-Stereoselctive and effective glycosylation with 5-thioglucopyranose was achieved by performing the reaction with pivaloyl- or benzoyl-protected glucopyranosyl trichloroacetimidates and BF3OEt2, a glycosyl activator, when C6-OH gluc