(2-azidophenyl)(4-chlorophenyl)selenide

Base Information

• Chemical Name: (2-azidophenyl)(4-chlorophenyl)selenide
• CAS No.: 1236252-99-5
• Molecular Formula: C₁₂H₈ClN₃Se
• Molecular Weight: 308.629
• Mol file: 1236252-99-5.mol

Synonyms:(2-azidophenyl)(4-chlorophenyl)selenide

Chemical Property of (2-azidophenyl)(4-chlorophenyl)selenide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2-azidophenyl)(4-chlorophenyl)selenide

There total 4 articles about (2-azidophenyl)(4-chlorophenyl)selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

C12H10ClNSe (1236252-90-6) → (2-azidophenyl)(4-chlorophenyl)selenide (1236252-99-5)

Guidance literature:

With trimethylsilylazide; isopentyl nitrite; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1016/j.tetlet.2010.04.076

Reference yield:

bis(p-chlorophenyl) diselenide (20541-49-5) → (2-azidophenyl)(4-chlorophenyl)selenide (1236252-99-5)

Guidance literature:

Multi-step reaction with 3 steps

1.1: sodium tetrahydroborate / ethanol; dimethyl sulfoxide

2.1: ammonium chloride; zinc / tetrahydrofuran

3.1: isopentyl nitrite / tetrahydrofuran / 0 °C

3.2: 0 - 20 °C / under air

With sodium tetrahydroborate; ammonium chloride; zinc; isopentyl nitrite; In tetrahydrofuran; ethanol; dimethyl sulfoxide;

DOI:10.1055/s-0030-1260083

Reference yield:

(4-chloro-phenyl)-(2-nitro-phenyl)-selenide (110166-81-9) → (2-azidophenyl)(4-chlorophenyl)selenide (1236252-99-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: ammonium chloride; zinc / tetrahydrofuran

2.1: isopentyl nitrite / tetrahydrofuran / 0 °C

2.2: 0 - 20 °C / under air

With ammonium chloride; zinc; isopentyl nitrite; In tetrahydrofuran;

DOI:10.1055/s-0030-1260083

upstream raw materials:

C₁₂H₁₀ClNSe

bis(p-chlorophenyl) diselenide

(4-chloro-phenyl)-(2-nitro-phenyl)-selenide

2-Chloronitrobenzene

Downstream raw materials:

1-{2-[(4-chlorophenyl)selanyl]phenyl}-4-phenyl-1H-1,2,3-triazole

ethyl 1-(2-(4-chlorophenylselanyl)phenyl)-5-methyl-1H-1,2,3-triazole-4-carboxylate

1-[2-(4-chlorophenylselanyl)phenyl]-5-methyl-N-phenyl-1H-1,2,3-triazole-4-carboxamide

Refernces

• 1、 Deobald, Anna Maria,Simon de Camargo, Leandro R.,Tabarelli, Greice,H?rner, Manfredo,Rodrigues, Oscar E.D.,Alves, Diego,Braga, Ant?nio L.. "Synthesis of azido arylselenides and azido aryldiselenides: a new class of selenium-nitrogen compounds". experimental part. p. 3364 - 3367. Retrieved 2010/08/19.