20541-49-5

Basic information

• Product Name: BIS(4-CHLOROPHENYL)DISELENIDE
• Synonyms: 1,2-BIS(4-CHLOROPHENYL)DISELANE;BIS(4-CHLOROBENZENE) DISELENIDE;BIS(4-CHLOROPHENYL)DISELENIDE;bis(p-chlorophenyl) diselenide;Diselenide, bis(4-chlorophenyl);4,4μ-Dichlorodiphenyl diselenide, 4-Chlorophenyl diselenide;4,4'-Diselenobis(chlorobenzene);Bis(4-chlorophenyl) perdiselenide
• CAS NO: 20541-49-5
• Molecular Formula: C₁₂H₈Cl₂Se₂
• Molecular Weight: 381.02
• EINECS: 243-864-6
• Mol File: 20541-49-5.mol
• Article Data: 48

Chemical Properties

• Melting Point: 85-88°C
• Boiling Point: 424.2°C at 760 mmHg
• Flash Point: 210.4°C
• Appearance: /solid
• Vapor Pressure: 5.19E-07mmHg at 25°C
• CAS DataBase Reference: BIS(4-CHLOROPHENYL)DISELENIDE(CAS DataBase Reference)
• NIST Chemistry Reference: BIS(4-CHLOROPHENYL)DISELENIDE(20541-49-5)
• EPA Substance Registry System: BIS(4-CHLOROPHENYL)DISELENIDE(20541-49-5)

Safety Data

• Hazard Codes: T,N
• Statements: 23/25-33-50/53
• Safety Statements: 20/21-28-45-60-61
• RIDADR: 2811
• HazardClass: 6.1(b)
• PackingGroup: III
• Hazardous Substances Data: 20541-49-5(Hazardous Substances Data)

Usage

Chemical Properties

Yellow crystalline powder

InChI:InChI=1/C12H8Cl2Se2/c13-9-1-5-11(6-2-9)15-16-12-7-3-10(14)4-8-12/h1-8H

Upstream product

• 20753-53-1 4-chlorobenzeneseleninic acid 
• 7314-73-0 1-chloro-4-selenocyanatobenzene 
• 42572-42-9 phenylselenium trichloride 
• 57878-20-3 p-chlorobenzeneselenenyl chloride 
• 856129-18-5 ethyl-dichloro-(4-chloro-phenyl)-λ⁴-selane 
• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 106-39-8 bromochlorobenzene 
• 34713-70-7 2-Phenylpropanal 
• 60805-87-0 p-chlorobenzeneselenenyl bromide 
• 63126-47-6 (2S)-2-(methoxymethyl)-1-pyrrolidine 
• 50630-24-5 β-(phenylseleno)ethyl chloride 
• 16645-10-6 p-chloroselenophenol 
• 2577-48-2 methyl (2S)-pyrrolidine carboxylate 
• 673-41-6 p-chlorobenzenediazonium tetrafluoroborate 

Downstream Products

• 20753-53-1 4-chlorobenzeneseleninic acid 
• 62635-83-0 p-chorophenylselenium trichloride 
• 53973-66-3 (4-chlorophenyl) dodecyl selenide 
• 82453-98-3 (Z)-2-(4-Chloro-phenylselanyl)-oct-2-enal 
• 147047-90-3 1-Chloro-4-hept-1-ynylselanyl-benzene 
• 115306-02-0 2-<(4-chlorophenyl)seleno>-1,3-dithiane 
• 82454-03-3 2-(4-Chloro-phenylselanyl)-3-methyl-1-phenyl-but-2-en-1-one 
• 74061-09-9 N-p-chlorobenzoyl-p-chlorobenzeneseleninimidoyl chloride 
• 60805-72-3 C₁₂H₉ClO₂SSe 
• 132591-63-0 6-(4-Chloro-phenylselanylmethyl)-1,4-dioxa-spiro[4.4]nonane 
• 145215-54-9 (+/-)-syn-2-[2-(4-chlorophenylselanyl)ethyl]-3-methyl-pent-4-ynoic acid 
• 80684-27-1 5-t-butyldimethylsiloxy-2-(p-chlorophenylseleno)-3-pentanone 
• 80684-24-8 5-t-butyldimethylsiloxy-3-(p-chlorophenylseleno)-2-pentanone 
• 145215-57-2 (+/-)-trans-5-[4-[2-(4-chlorophenylselanyl)ethyl]-3-methyl-5-oxo-1,5-dihydropyrrol-2-ylidenemethyl]-3-(2-methoxycarbonylethyl)-4-methyl-1H-pyrrole-2-carboxylic acid, tert-butyl ester 

Relevant articles and documents

Blue light-promoted radical sulfoximido-chalcogenization of aliphatic and aromatic alkenes

A transition metal-free synthesis ofN-(arylthio/seleno)ethyl sulfoxidminesviablue light-promoted radical sulfoximido-chalcogenization of aliphatic and aromatic alkenes was developed. The sulfoximidation process demonstrated high chemoselectivity and allowed a broad substrate scope, completing the sulfoximido-chalcogenization of alkenes in good yields.

Preparation of selenofunctionalized heterocycles via iodosobenzene-mediated intramolecular selenocyclizations of olefins with diselenides

An intramolecular selenocyclizations of olefins mediated by a commercially available hypervalent iodine(III) reagent, PhIO, was developed. This method provided access to a wide range of selenenylated heterocycles under ambient conditions. The striking advantages of this protocol over all previous methods include mild reaction conditions, easy operation, good yields, high levels of functional group compatibility, large–scale application and suitability for the late-stage functionalization of complex molecules of biological importance.

FeCl3-catalyzed three-component aryl-selenylation of alkenes

FeCl3-catalyzed three-component aryl-selenylation of alkenes with good to excellent yields has been disclosed. This method is characterized by synthesis of complicated products in a single-step reaction, simple operation and readily available commercially reagents. Finally, a reasonable mechanism of FeCl3-catalyzed aryl-selenylation is proposed.