N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine

Base Information

Chemical Name:N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine
CAS No.:117942-50-4
Molecular Formula:C₂₀H₃₁NO₇Si
Molecular Weight:425.554
Hs Code.:

Synonyms:N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine

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Technology Process of N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine

There total 7 articles about N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 117942-45-7
N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine ethyl ester

: 117942-50-4
N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine

Guidance literature:: With sodium hydroxide; water; In ethanol; 1.) reflux, 2 h, 2.) RT, 20 h;
DOI:10.1021/jo00262a033

Reference yield:

: 117942-42-4
diethyl 4-<(2-methoxyethoxy)methoxy>benzalmalonate

: 117942-50-4
N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine

Guidance literature:: Multi-step reaction with 5 steps

1: 76 percent / dimethylsulfoxide; tetrahydrofuran / 1.) RT, 1 h, 2.) 50 deg C, 1 h

2: 78 percent / NaOH, H₂O / ethanol / 48 h / Ambient temperature

3: DPPA, Et₂N / toluene / 1 h / Heating

4: toluene / 20 h

5: 70 percent / NaOH, H₂O / ethanol / 1.) reflux, 2 h, 2.) RT, 20 h

With sodium hydroxide; diphenyl-phosphinic acid; water; diethylamine; In tetrahydrofuran; ethanol; dimethyl sulfoxide; toluene;
DOI:10.1021/jo00262a033

Reference yield:

: 117942-44-6
(Z)-1-(ethoxycarbonyl)-2-<4-<(2-methoxyethoxy)methoxy>phenyl>cyclopropanecarboxylic acid

: 117942-50-4
N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine

Guidance literature:: Multi-step reaction with 3 steps

1: DPPA, Et₂N / toluene / 1 h / Heating

2: toluene / 20 h

3: 70 percent / NaOH, H₂O / ethanol / 1.) reflux, 2 h, 2.) RT, 20 h

With sodium hydroxide; diphenyl-phosphinic acid; water; diethylamine; In ethanol; toluene;
DOI:10.1021/jo00262a033