diethyl (+)-(4R)-(3,3,4-trimethylcyclohex-1-en-1-yl)phosphoric triester

Base Information

Chemical Name:diethyl (+)-(4R)-(3,3,4-trimethylcyclohex-1-en-1-yl)phosphoric triester
CAS No.:179944-22-0
Molecular Formula:C₁₃H₂₅O₄P
Molecular Weight:276.313
Hs Code.:

Synonyms:diethyl (+)-(4R)-(3,3,4-trimethylcyclohex-1-en-1-yl)phosphoric triester

Suppliers and Price of diethyl (+)-(4R)-(3,3,4-trimethylcyclohex-1-en-1-yl)phosphoric triester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of diethyl (+)-(4R)-(3,3,4-trimethylcyclohex-1-en-1-yl)phosphoric triester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of diethyl (+)-(4R)-(3,3,4-trimethylcyclohex-1-en-1-yl)phosphoric triester

There total 1 articles about diethyl (+)-(4R)-(3,3,4-trimethylcyclohex-1-en-1-yl)phosphoric triester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 917-54-4
methyllithium

: 89162-97-0
(R)-(+)-3,4-dimethyl-2-cyclohexen-1-one

: 814-49-3
diethyl chlorophosphate

: 179944-22-0
diethyl (+)-(4R)-(3,3,4-trimethylcyclohex-1-en-1-yl)phosphoric triester

Guidance literature:: methyllithium; With copper(l) cyanide; In diethyl ether; at -30 - -20 ℃; for 1h;

(R)-(+)-3,4-dimethyl-2-cyclohexen-1-one; In diethyl ether; at -78 - -30 ℃; for 1h;

diethyl chlorophosphate; With N,N,N,N,N,N-hexamethylphosphoric triamide; In tetrahydrofuran; diethyl ether; at -30 - 20 ℃; for 12h;
DOI:10.1021/jo960392l

Reference yield: 85.0%

: 13170-43-9
(trimethylsilyl)methylmagnesium chloride

: 179944-22-0
diethyl (+)-(4R)-(3,3,4-trimethylcyclohex-1-en-1-yl)phosphoric triester

: 179944-23-1
(+)-(4R)-trimethyl[(3,3,4-trimethylcyclohex-1-en-1-yl)methyl]silane

Guidance literature:: bis(acetylacetonate)nickel(II); In tetrahydrofuran; diethyl ether; at 20 ℃; for 11h;
DOI:10.1021/jo960392l

Reference yield:

: 179944-22-0
diethyl (+)-(4R)-(3,3,4-trimethylcyclohex-1-en-1-yl)phosphoric triester

: 82890-08-2
(3E)-4-[(1R,3R)-2,2,3-trimethyl-6-methylidenecyclohexyl]but-3-en-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / nickel acetylacetonate / tetrahydrofuran; diethyl ether / 11 h / 20 °C

2: ZnI₂

3: 93 percent / TiCl₄ / CH₂Cl₂ / 1 h / -70 °C

With titanium tetrachloride; bis(acetylacetonate)nickel(II); zinc(II) iodide; In tetrahydrofuran; diethyl ether; dichloromethane; 1: Substitution / 2: H-ene reaction / 3: protodesilylation;
DOI:10.1021/jo960392l