triethyl((E,3S,4R)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]-5,8-dien-3-yloxy)silane

Base Information

Chemical Name:triethyl((E,3S,4R)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]-5,8-dien-3-yloxy)silane
CAS No.:918637-22-6
Molecular Formula:C₂₆H₄₅NO₂SSi
Molecular Weight:463.8
Hs Code.:

Synonyms:triethyl((E,3S,4R)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]-5,8-dien-3-yloxy)silane

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Chemical Property of triethyl((E,3S,4R)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]-5,8-dien-3-yloxy)silane

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Technology Process of triethyl((E,3S,4R)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]-5,8-dien-3-yloxy)silane

There total 1 articles about triethyl((E,3S,4R)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]-5,8-dien-3-yloxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 918637-19-1
C₂₃H₄₁NO₂SSi

: 106-95-6
allyl bromide

: 918637-22-6
triethyl((E,3S,4R)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]-5,8-dien-3-yloxy)silane

Guidance literature:: C₂₃H₄₁NO₂SSi; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 0 ℃; Inert atmosphere;

allyl bromide; In tetrahydrofuran; hexane; at -45 - 20 ℃; for 3h; Inert atmosphere;
DOI:10.1002/chem.201103060

Reference yield: 95.0%

: 918637-22-6
triethyl((E,3S,4R)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]-5,8-dien-3-yloxy)silane

: 918637-44-2
(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-ol

Guidance literature:: With pyridine hydrogenfluoride; In tetrahydrofuran; water; at 20 ℃; for 3h; Inert atmosphere;
DOI:10.1002/chem.201103060

Reference yield:

: 918637-22-6
triethyl((E,3S,4R)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]-5,8-dien-3-yloxy)silane

: 1380216-03-4
(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-yl but-3-enoate

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine hydrogenfluoride / tetrahydrofuran; water / 3 h / 20 °C / Inert atmosphere

2: dmap; dicyclohexyl-carbodiimide / dichloromethane / 12 h / 0 - 25 °C / Inert atmosphere

With dmap; pyridine hydrogenfluoride; dicyclohexyl-carbodiimide; In tetrahydrofuran; dichloromethane; water;
DOI:10.1002/chem.201103060