(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-ol

Base Information

Chemical Name:(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-ol
CAS No.:918637-44-2
Molecular Formula:C₂₀H₃₁NO₂S
Molecular Weight:349.538
Hs Code.:

Synonyms:(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-ol

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Technology Process of (3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-ol

There total 2 articles about (3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 918637-22-6
triethyl((E,3S,4R)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]-5,8-dien-3-yloxy)silane

: 918637-44-2
(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-ol

Guidance literature:: With pyridine hydrogenfluoride; In tetrahydrofuran; water; at 20 ℃; for 3h; Inert atmosphere;
DOI:10.1002/chem.201103060

Reference yield:

: 918637-19-1
C₂₃H₄₁NO₂SSi

: 918637-44-2
(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 0 °C / Inert atmosphere

1.2: 3 h / -45 - 20 °C / Inert atmosphere

2.1: pyridine hydrogenfluoride / tetrahydrofuran; water / 3 h / 20 °C / Inert atmosphere

With n-butyllithium; pyridine hydrogenfluoride; In tetrahydrofuran; hexane; water;
DOI:10.1002/chem.201103060

Reference yield: 67.0%

: 591-80-0
pent-4-enoic acid

: 918637-44-2
(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-ol

: 918637-46-4
(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-yl pent-4-enoate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 - 25 ℃; for 12h; Inert atmosphere;
DOI:10.1002/chem.201103060