(tetraphenylporphyrin)Fe(CH₃)

Base Information

• Chemical Name: (tetraphenylporphyrin)Fe(CH₃)
• CAS No.: 79197-95-8
• Molecular Formula: C₄₅H₃₁FeN₄
• Molecular Weight: 683.615
• Mol file: 79197-95-8.mol

Synonyms:(tetraphenylporphyrin)Fe(CH₃)

Chemical Property of (tetraphenylporphyrin)Fe(CH₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (tetraphenylporphyrin)Fe(CH₃)

There total 7 articles about (tetraphenylporphyrin)Fe(CH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8) → (tetraphenylporphyrin)Fe(CH3) (79197-95-8)

Guidance literature:

With methyl magnesium iodide; In benzene; 1 equiv of benzene soln. of MeMgI was added dropwise under vigorous stirring at 5-6°C under inert atmosphere to a soln. of Fe-complex inbenzene, the mixt. was stirred for several min; hydrolyzed with Ar-satd. water, org. phase was washed until neutral, dried (MgSO4), evapd. in vacuo below 40°C, residue was chromd. overAl2O3 (benzene) in the dark, recrystd. from C6H6-heptane, dried for 24 h at 65°C/0.1 mmHg; elem. anal.;

DOI:10.1016/0022-328X(83)80109-0

Reference yield:

Fe((C4NH2CC6H5)4)(CH3NNH)2 (84680-92-2) → (tetraphenylporphyrin)Fe(CH3) (79197-95-8)

Guidance literature:

With O₂ or FeCl₃; In dichloromethane; limited amounts of O2; UV, NMR;

DOI:10.1021/ja00343a070

Reference yield:

meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8) + trimethylsilyllithium (18000-27-6) → ((5,10,15,20-tetraphenylporphyrinato)iron(III))2O (12582-61-5) + (tetraphenylporphyrin)Fe(CH3) (79197-95-8) + trimethylsilyliron(III)tetraphenylporphyrin + hexamethylphosphoramide-iron(II)tetraphenylporphyrin-complex (118317-88-7)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; In N,N,N,N,N,N-hexamethylphosphoric triamide; toluene; react. at room temp.;

DOI:10.1021/ja00234a027

upstream raw materials:

Na⁽¹⁺⁾*Fe(C₂₀H₈N₄(C₆H₅)4)^(1-)=Na(Fe(C₂₀H₈N₄(C₆H₅)4))

meso-tetraphenylporphyrin iron(III) chloride

methylhydrazine

Fe((C₄NH₂CC₆H₅)4)(CH₃NNH)2

Downstream raw materials:

μ-oxo-bis[α,β,γ,δ-tetraphenylporphinatoiron]

meso-tetraphenylporphyrin iron(III) chloride

5,10,15,20-tetraphenyl porphyrin iron

Fe(C₂₀H₈N₃(C₆H₅)4N(CH₃))Cl