tert-butyl((R)-4-(4-methoxybenzyloxy)-1-((S)-oxiran-2-yl)butan-2-yloxy)dimethylsilane

Base Information

Chemical Name:tert-butyl((R)-4-(4-methoxybenzyloxy)-1-((S)-oxiran-2-yl)butan-2-yloxy)dimethylsilane
CAS No.:1227514-61-5
Molecular Formula:C₂₀H₃₄O₄Si
Molecular Weight:366.573
Hs Code.:

Synonyms:tert-butyl((R)-4-(4-methoxybenzyloxy)-1-((S)-oxiran-2-yl)butan-2-yloxy)dimethylsilane

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Chemical Property of tert-butyl((R)-4-(4-methoxybenzyloxy)-1-((S)-oxiran-2-yl)butan-2-yloxy)dimethylsilane

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Technology Process of tert-butyl((R)-4-(4-methoxybenzyloxy)-1-((S)-oxiran-2-yl)butan-2-yloxy)dimethylsilane

There total 2 articles about tert-butyl((R)-4-(4-methoxybenzyloxy)-1-((S)-oxiran-2-yl)butan-2-yloxy)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

: tert-butyl((R)-4-(4-methoxybenzyloxy)-1-(oxiran-2-yl)butan-2-yloxy)dimethylsilane

: 1227514-61-5
tert-butyl((R)-4-(4-methoxybenzyloxy)-1-((S)-oxiran-2-yl)butan-2-yloxy)dimethylsilane

: C₂₀H₃₆O₅Si

Guidance literature:: With [(S,S)-N,N-bis-(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-Co(III)-acetate]; water; In tetrahydrofuran; at 0 ℃; for 24h; Resolution of racemate;
DOI:10.1016/j.tet.2010.02.093

Reference yield:

: 380909-41-1
(S)-tert-butyl((1-((4-methoxybenzyl)oxy)hex-5-en-3-yl)oxy)dimethylsilane

: tert-butyl((R)-4-(4-methoxybenzyloxy)-1-((R)-oxiran-2-yl)butan-2-yloxy)dimethylsilane

: 1227514-61-5
tert-butyl((R)-4-(4-methoxybenzyloxy)-1-((S)-oxiran-2-yl)butan-2-yloxy)dimethylsilane

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 - 20 ℃; optical yield given as %de; Inert atmosphere;
DOI:10.1016/j.tet.2010.02.093

Reference yield: 85.0%

: 1227514-61-5
tert-butyl((R)-4-(4-methoxybenzyloxy)-1-((S)-oxiran-2-yl)butan-2-yloxy)dimethylsilane

: 1774-47-6
trimethylsulfoxonium iodide

: 1227514-62-6
(3S,5R)-5-(tert-butyldimethylsilyloxy)-7-(4-methoxybenzyloxy)-hept-1-en-3-ol

Guidance literature:: trimethylsulfoxonium iodide; With n-butyllithium; In tetrahydrofuran; at -20 ℃; for 0.666667h; Inert atmosphere;

tert-butyl((R)-4-(4-methoxybenzyloxy)-1-((S)-oxiran-2-yl)butan-2-yloxy)dimethylsilane; In tetrahydrofuran; at -20 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2010.02.093