3-O-benzyl-6,7-dideoxy-4-O-(4-methoxybenzyl)-1,2-(1-methoxy-ethylidene-β-L-ido-hepta-6-enofuranose

Base Information

Chemical Name:3-O-benzyl-6,7-dideoxy-4-O-(4-methoxybenzyl)-1,2-(1-methoxy-ethylidene-β-L-ido-hepta-6-enofuranose
CAS No.:628280-95-5
Molecular Formula:C₂₅H₃₀O₇
Molecular Weight:442.509
Hs Code.:

Synonyms:3-O-benzyl-6,7-dideoxy-4-O-(4-methoxybenzyl)-1,2-(1-methoxy-ethylidene-β-L-ido-hepta-6-enofuranose

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Chemical Property of 3-O-benzyl-6,7-dideoxy-4-O-(4-methoxybenzyl)-1,2-(1-methoxy-ethylidene-β-L-ido-hepta-6-enofuranose

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Technology Process of 3-O-benzyl-6,7-dideoxy-4-O-(4-methoxybenzyl)-1,2-(1-methoxy-ethylidene-β-L-ido-hepta-6-enofuranose

There total 8 articles about 3-O-benzyl-6,7-dideoxy-4-O-(4-methoxybenzyl)-1,2-(1-methoxy-ethylidene-β-L-ido-hepta-6-enofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 824-94-2
p-methoxybenzyl chloride

: 628280-95-5
3-O-benzyl-6,7-dideoxy-4-O-(4-methoxybenzyl)-1,2-(1-methoxy-ethylidene-β-L-ido-hepta-6-enofuranose

Guidance literature:: 4-O-acetyl-3-O-benzyl-6,7-dideoxy-1,2-(1-methoxyethylidene)-β-L-ido-hepta-6-enopyranose; With sodium methylate; In methanol;

p-methoxybenzyl chloride; With sodium hydride;

Reference yield:

: 106221-09-4
(S)-1-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-prop-2-en-1-ol

: 628280-95-5
3-O-benzyl-6,7-dideoxy-4-O-(4-methoxybenzyl)-1,2-(1-methoxy-ethylidene-β-L-ido-hepta-6-enofuranose

Guidance literature:: Multi-step reaction with 4 steps

1.1: AcOH; water / 12 h / 80 °C

1.2: 7.67 g / pyridine / 16 h / 20 °C

2.1: TMSBr / CH₂Cl₂ / 2 h / 20 °C

2.2: CH₂Cl₂ / 12 h / Heating

3.1: MeONa / methanol / 20 h / 20 °C

4.1: 1.16 g / dimethylformamide / 1 h / 20 °C

With trimethylsilyl bromide; water; sodium methylate; acetic acid; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/ejoc.200300254

Reference yield:

: 262382-48-9
1,2,4-tri-O-acetyl-3-O-benzyl-6,7-dideoxy-α,β-L-ido-hepta-6-eno-pyranose

: 628280-95-5
3-O-benzyl-6,7-dideoxy-4-O-(4-methoxybenzyl)-1,2-(1-methoxy-ethylidene-β-L-ido-hepta-6-enofuranose

Guidance literature:: Multi-step reaction with 3 steps

1.1: TMSBr / CH₂Cl₂ / 2 h / 20 °C

1.2: CH₂Cl₂ / 12 h / Heating

2.1: MeONa / methanol / 20 h / 20 °C

3.1: 1.16 g / dimethylformamide / 1 h / 20 °C

With trimethylsilyl bromide; sodium methylate; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/ejoc.200300254