1-[(4aR,11cR)-4a-Ethyl-7-(4-methoxy-benzenesulfonyl)-2,3,4,4a,5,6,7,11c-octahydro-pyrido[3,2-c]carbazol-1-yl]-2-phenylsulfanyl-ethanone

Base Information

Chemical Name:1-[(4aR,11cR)-4a-Ethyl-7-(4-methoxy-benzenesulfonyl)-2,3,4,4a,5,6,7,11c-octahydro-pyrido[3,2-c]carbazol-1-yl]-2-phenylsulfanyl-ethanone
CAS No.:85924-16-9
Molecular Formula:C₃₂H₃₄N₂O₄S₂
Molecular Weight:574.765
Hs Code.:

Synonyms:1-[(4aR,11cR)-4a-Ethyl-7-(4-methoxy-benzenesulfonyl)-2,3,4,4a,5,6,7,11c-octahydro-pyrido[3,2-c]carbazol-1-yl]-2-phenylsulfanyl-ethanone

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Chemical Property of 1-[(4aR,11cR)-4a-Ethyl-7-(4-methoxy-benzenesulfonyl)-2,3,4,4a,5,6,7,11c-octahydro-pyrido[3,2-c]carbazol-1-yl]-2-phenylsulfanyl-ethanone

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Technology Process of 1-[(4aR,11cR)-4a-Ethyl-7-(4-methoxy-benzenesulfonyl)-2,3,4,4a,5,6,7,11c-octahydro-pyrido[3,2-c]carbazol-1-yl]-2-phenylsulfanyl-ethanone

There total 2 articles about 1-[(4aR,11cR)-4a-Ethyl-7-(4-methoxy-benzenesulfonyl)-2,3,4,4a,5,6,7,11c-octahydro-pyrido[3,2-c]carbazol-1-yl]-2-phenylsulfanyl-ethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 7031-27-8
(phenylthio)acetic acid chloride

: 85924-14-7
cis-4a-ethyl-2,3,4,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1H-pyrido<3,2-c>carbazole

: 85924-16-9
1-[(4aR,11cR)-4a-Ethyl-7-(4-methoxy-benzenesulfonyl)-2,3,4,4a,5,6,7,11c-octahydro-pyrido[3,2-c]carbazol-1-yl]-2-phenylsulfanyl-ethanone

Guidance literature:: With sodium hydroxide; In dichloromethane; at 0 ℃; for 0.25h;
DOI:10.1021/ja00352a038

Reference yield:

: 85923-70-2
2,2,2-trichloroethyl cis-2,3,4,4a,5,6,7,11c-octahydro-4a-ethyl-7-<(p-methoxyphenyl)sulfonyl>-1H-pyrido<3,2-c>carbazole-1-carboxylate

: 85924-16-9
1-[(4aR,11cR)-4a-Ethyl-7-(4-methoxy-benzenesulfonyl)-2,3,4,4a,5,6,7,11c-octahydro-pyrido[3,2-c]carbazol-1-yl]-2-phenylsulfanyl-ethanone

Guidance literature:: Multi-step reaction with 2 steps

1: 71 percent / zinc, acetic acid / H₂O / 4 h

2: 50 percent / aq. NaOH / CH₂Cl₂ / 0.25 h / 0 °C

With sodium hydroxide; acetic acid; zinc; In dichloromethane; water;
DOI:10.1021/ja00352a038

Reference yield:

: 85924-16-9
1-[(4aR,11cR)-4a-Ethyl-7-(4-methoxy-benzenesulfonyl)-2,3,4,4a,5,6,7,11c-octahydro-pyrido[3,2-c]carbazol-1-yl]-2-phenylsulfanyl-ethanone

: 85924-15-8
2-(phenylsulfinyl)acetyl-cis-4a-ethyl-2,3,4,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1H-pyrido<3,2-c>carbazole

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 1.25h; Yield given;
DOI:10.1021/ja00352a038