(1E)-2-[1-phenyl-4-(tert-butyldimethylsilyloxy)butoxy]vinylsulfonylbenzene

Base Information

Chemical Name:(1E)-2-[1-phenyl-4-(tert-butyldimethylsilyloxy)butoxy]vinylsulfonylbenzene
CAS No.:285545-72-4
Molecular Formula:C₂₄H₃₄O₄SSi
Molecular Weight:446.683
Hs Code.:

Synonyms:(1E)-2-[1-phenyl-4-(tert-butyldimethylsilyloxy)butoxy]vinylsulfonylbenzene

Suppliers and Price of (1E)-2-[1-phenyl-4-(tert-butyldimethylsilyloxy)butoxy]vinylsulfonylbenzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1E)-2-[1-phenyl-4-(tert-butyldimethylsilyloxy)butoxy]vinylsulfonylbenzene

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Technology Process of (1E)-2-[1-phenyl-4-(tert-butyldimethylsilyloxy)butoxy]vinylsulfonylbenzene

There total 1 articles about (1E)-2-[1-phenyl-4-(tert-butyldimethylsilyloxy)butoxy]vinylsulfonylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 963-16-6
(E)-1,2-bis(phenylsulfonyl)ethylene

: 137333-75-6
4-tert-butyldimethylsilyloxy-1-phenylbutan-1-ol

: 285545-72-4
(1E)-2-[1-phenyl-4-(tert-butyldimethylsilyloxy)butoxy]vinylsulfonylbenzene

Guidance literature:: With lithium hexamethyldisilazane; In tetrahydrofuran; at 0 - 20 ℃; for 3h;
DOI:10.1021/jo991970b

Reference yield: 87.0%

: 285545-72-4
(1E)-2-[1-phenyl-4-(tert-butyldimethylsilyloxy)butoxy]vinylsulfonylbenzene

: 285545-74-6
4-[(1E)-2-(phenylsulfonyl)vinyloxy]-4-phenylbutanoic acid

Guidance literature:: With jones reagent; In acetone; at -10 - 20 ℃; for 16h;
DOI:10.1021/jo991970b

Reference yield:

: 285545-72-4
(1E)-2-[1-phenyl-4-(tert-butyldimethylsilyloxy)butoxy]vinylsulfonylbenzene

: (2S*,6R*)-6-phenyl-2-[(phenylsulfonyl)methyl]-4,5,6-trihydro-2H-pyran-3-one

Guidance literature:: Multi-step reaction with 3 steps

1.1: 87 percent / Jones reagent / acetone / 16 h / -10 - 20 °C

2.1: Et₃N / CH₂Cl₂ / 0.5 h / 0 - 20 °C

2.2: 82 percent / PBu₃ / tetrahydrofuran / 19 h / 0 - 20 °C

3.1: Et₃B; (TMS)3SiH / benzene; hexane / 20 °C

With jones reagent; triethyl borane; tris-(trimethylsilyl)silane; triethylamine; In hexane; dichloromethane; acetone; benzene; 1.1: Oxidation / 2.1: Substitution / 2.2: Substitution / 3.1: Cyclization;
DOI:10.1021/jo991970b