η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-dithiolato]rhodium

Base Information

Chemical Name:η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-dithiolato]rhodium
CAS No.:251316-70-8
Molecular Formula:C₁₂H₂₅B₁₀RhS₂
Molecular Weight:444.478
Hs Code.:

Synonyms:η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-dithiolato]rhodium

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-dithiolato]rhodium

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Technology Process of η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-dithiolato]rhodium

There total 2 articles about η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-dithiolato]rhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (C₅(CH₃)5RhS₂C₂B₁₀H₁₀)2(CH₃O₂CCCH)2

: 922-67-8
propynoic acid methyl ester

: 251316-70-8
η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-dithiolato]rhodium

: 2672-58-4
1,3,5-tris-(methoxycarbonyl)benzene

: 2459-10-1
benzene-1,2,4-tricarboxylic acid trimethyl ester

Guidance literature:: In toluene; the mixt. in toluene was heated at 70°C for 24 h; solvent was removed, not sepd., detected by NMR spectra;
DOI:10.1021/om0003077

Reference yield:

: C₅(CH₃)5RhS₂C₂B₁₀H₁₀CHC₂(CO₂CH₃)2CH

: 922-67-8
propynoic acid methyl ester

: 251316-70-8
η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-dithiolato]rhodium

: 2672-58-4
1,3,5-tris-(methoxycarbonyl)benzene

: 2459-10-1
benzene-1,2,4-tricarboxylic acid trimethyl ester

Guidance literature:: In toluene; the mixt. in toluene was heated at 70°C for 24 h; evapd., not sepd., detected by NMR spectra;
DOI:10.1021/om0003077

Reference yield: 88.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 109-72-8,29786-93-4
n-butyllithium

: 251316-70-8
η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-dithiolato]rhodium

: 7732-18-5
water

: 108-98-5
thiophenol

: 957671-84-0
(C₅(CH₃)5)Rh(S₂C₂B₁₀H₁₀)(SC₆H₅)^(1-)*Li(H₂O)2(C₄H₈O)2⁽¹⁺⁾=Li(H₂O)2(C₄H₈O)2(C₅(CH₃)5)Rh(S₂C₂B₁₀H₁₀)(SC₆H₅)

Guidance literature:: In tetrahydrofuran; diethyl ether; (N2, Schlenk) a soln. of C6H5SH in diethyl ether was lithiated with n-C4H9Li, the mixt. was stirred for 1 h at room temp., a soln. of Rh-complexin THF was added at ambient temp., the soln. was stirred for 16 h; the solvent was removed under vac., the residue was recrystd. with THF at -28°C; elem. anal.;
DOI:10.1021/om7004035