(2E,8E)-10-(tert-Butyl-diphenyl-silanyloxy)-2,8-dimethyl-deca-2,8-dienal

Base Information

Chemical Name:(2E,8E)-10-(tert-Butyl-diphenyl-silanyloxy)-2,8-dimethyl-deca-2,8-dienal
CAS No.:882165-13-1
Molecular Formula:C₂₈H₃₈O₂Si
Molecular Weight:434.694
Hs Code.:

Synonyms:(2E,8E)-10-(tert-Butyl-diphenyl-silanyloxy)-2,8-dimethyl-deca-2,8-dienal

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Chemical Property of (2E,8E)-10-(tert-Butyl-diphenyl-silanyloxy)-2,8-dimethyl-deca-2,8-dienal

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Technology Process of (2E,8E)-10-(tert-Butyl-diphenyl-silanyloxy)-2,8-dimethyl-deca-2,8-dienal

There total 10 articles about (2E,8E)-10-(tert-Butyl-diphenyl-silanyloxy)-2,8-dimethyl-deca-2,8-dienal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 882165-38-0
(2E,8E)-10-(tert-Butyl-diphenyl-silanyloxy)-2,8-dimethyl-deca-2,8-dien-1-ol

: 882165-13-1
(2E,8E)-10-(tert-Butyl-diphenyl-silanyloxy)-2,8-dimethyl-deca-2,8-dienal

Guidance literature:: With Dess-Martin periodane; In dichloromethane; at 20 ℃; for 0.5h;
DOI:10.1021/ol060221v

Reference yield:

: 882165-43-7
8-(tert-butyl-diphenyl-silanyloxy)-6-methyl-oct-6-enal

: 882165-13-1
(2E,8E)-10-(tert-Butyl-diphenyl-silanyloxy)-2,8-dimethyl-deca-2,8-dienal

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / toluene / 4 h / 80 °C

2: 92 percent / DIBALH / toluene / 3 h / -78 °C

3: 90 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.5 h / 20 °C

With diisobutylaluminium hydride; Dess-Martin periodane; In dichloromethane; toluene; 3: Dess-Martin oxidation;
DOI:10.1021/ol060221v

Reference yield:

: 882165-41-5
(2E,6E)-8-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-octa-2,6-dienoic acid methyl ester

: 882165-13-1
(2E,8E)-10-(tert-Butyl-diphenyl-silanyloxy)-2,8-dimethyl-deca-2,8-dienal

Guidance literature:: Multi-step reaction with 5 steps

1: 68 percent / BiCl₅; NaBH₄ / 4 h / 20 °C

2: 82 percent / DIBALH / toluene / 3 h / -78 °C

3: 85 percent / toluene / 4 h / 80 °C

4: 92 percent / DIBALH / toluene / 3 h / -78 °C

5: 90 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.5 h / 20 °C

With sodium tetrahydroborate; bismuth (V) chloride; diisobutylaluminium hydride; Dess-Martin periodane; In dichloromethane; toluene; 5: Dess-Martin oxidation;
DOI:10.1021/ol060221v