3,7,13-tri(p-toluenesulfonyl)-3,7,13-triazapentadecanedinitril

Base Information

• Chemical Name: 3,7,13-tri(p-toluenesulfonyl)-3,7,13-triazapentadecanedinitril
• CAS No.: 76980-36-4
• Molecular Formula: C₃₃H₄₁N₅O₆S₃
• Molecular Weight: 699.916
• Mol file: 76980-36-4.mol

Synonyms:3,7,13-tri(p-toluenesulfonyl)-3,7,13-triazapentadecanedinitril

Chemical Property of 3,7,13-tri(p-toluenesulfonyl)-3,7,13-triazapentadecanedinitril

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,7,13-tri(p-toluenesulfonyl)-3,7,13-triazapentadecanedinitril

There total 2 articles about 3,7,13-tri(p-toluenesulfonyl)-3,7,13-triazapentadecanedinitril which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

1,5,9-Tritosyl-1,5,9-triazanonane (35980-64-4) + acrylonitrile (107-13-1,25014-41-9) → 3,7,13-tri(p-toluenesulfonyl)-3,7,13-triazapentadecanedinitril (76980-36-4)

Guidance literature:

In N,N-dimethyl-formamide;

DOI:10.1021/ja00395a077

Reference yield:

p-toluenesulfonyl chloride (98-59-9) → 3,7,13-tri(p-toluenesulfonyl)-3,7,13-triazapentadecanedinitril (76980-36-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 95 percent / K₂CO₃ / H₂O / 3 h / 60 °C

2: 78 percent / K₂CO₃ / dimethylformamide / 4 h / Ambient temperature

With potassium carbonate; In water; N,N-dimethyl-formamide;

DOI:10.1002/hlca.19830660426

Reference yield: 95.0%

3,7,13-tri(p-toluenesulfonyl)-3,7,13-triazapentadecanedinitril (76980-36-4) → 4,8,12-tri(p-toluenesulfonyl)-4,8,12-triazapentadecane-1,15-diamine (76980-37-5)

Guidance literature:

With diborane; In tetrahydrofuran;

DOI:10.1021/ja00395a077

upstream raw materials:

1,5,9-Tritosyl-1,5,9-triazanonane

acrylonitrile

p-toluenesulfonyl chloride

Downstream raw materials:

4,8,12-tri(p-toluenesulfonyl)-4,8,12-triazapentadecane-1,15-diamine

N,N',4,8,12-penta(p-toluenesulfonyl)-4,8,12-triazapentadecane-1,15-diamine