methyl 3-<2-<(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)oxy>phenyl>phenylacetate

Base Information

Chemical Name:methyl 3-<2-<(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)oxy>phenyl>phenylacetate
CAS No.:173204-11-0
Molecular Formula:C₂₉H₃₂O₁₂
Molecular Weight:572.566
Hs Code.:

Synonyms:methyl 3-<2-<(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)oxy>phenyl>phenylacetate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 3-<2-<(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)oxy>phenyl>phenylacetate

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Technology Process of methyl 3-<2-<(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)oxy>phenyl>phenylacetate

There total 7 articles about methyl 3-<2-<(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)oxy>phenyl>phenylacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 171905-58-1
methyl [3-(2-hydroxyphenyl)phenyl]acetate

: 4163-65-9
per-O-acetyl-α-D-mannopyranose

: 173204-11-0
methyl 3-<2-<(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)oxy>phenyl>phenylacetate

Guidance literature:: With boron trifluoride diethyl etherate; In 1,2-dichloro-ethane; Ambient temperature;
DOI:10.1021/jm00026a004

Reference yield:

: 1878-67-7
3-Bromophenylacetic acid

: 173204-11-0
methyl 3-<2-<(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)oxy>phenyl>phenylacetate

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / H₂SO₄ / Heating

2: 96 percent / Na₂CO₃ / Pd(PPh₃)4 / toluene; H₂O / 16 h / Heating

3: 60 percent / BBr₃ / CH₂Cl₂ / 10 h / -10 °C

4: BF₃*Et₂O / 1,2-dichloro-ethane / 24 h / 20 °C

With boron tribromide; sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; sulfuric acid; boron trifluoride diethyl etherate; In dichloromethane; water; 1,2-dichloro-ethane; toluene;
DOI:10.1002/1099-0690(200212)2002:23<3966::AID-EJOC3966>3.0.CO;2-P

Reference yield:

: 150529-73-0
methyl 2-(3-bromophenyl)acetatee

: 173204-11-0
methyl 3-<2-<(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)oxy>phenyl>phenylacetate

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / Na₂CO₃ / Pd(PPh₃)4 / toluene; H₂O / 16 h / Heating

2: 60 percent / BBr₃ / CH₂Cl₂ / 10 h / -10 °C

3: BF₃*Et₂O / 1,2-dichloro-ethane / 24 h / 20 °C

With boron tribromide; sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; boron trifluoride diethyl etherate; In dichloromethane; water; 1,2-dichloro-ethane; toluene;
DOI:10.1002/1099-0690(200212)2002:23<3966::AID-EJOC3966>3.0.CO;2-P