sodium tetracarbonyl cobaltate

Base Information

• Chemical Name: sodium tetracarbonyl cobaltate
• CAS No.: 14878-28-5
• Molecular Formula: C₄CoO₄*Na
• Molecular Weight: 194.025
• Mol file: 14878-28-5.mol

Synonyms:sodium tetracarbonyl cobaltate

Chemical Property of sodium tetracarbonyl cobaltate

Chemical Property:

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of sodium tetracarbonyl cobaltate

There total 10 articles about sodium tetracarbonyl cobaltate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.05%

[Dicarbonyl[bis(diphenylphosphanyl)amin-κ(2)P][bis(diphenylphosphanyl)amin-κP] cobalt(I)-tetracarbonylcobaltat(-I)]-Dioxan(4/3) + sodium tetraphenyl borate (143-66-8) → sodium tetracarbonyl cobaltate (14878-28-5) + [Carbonylbis[bis(diphenylphosphanyl)amin-κ(2)P]cobalt(I)-tetraphenylborat(III)]-Tetrahydrofuran(1/1)

Guidance literature:

In tetrahydrofuran; byproducts: CO, dioxane; under N2; addn. of NaBPh4 to THF soln. of Co-complex, warming to 50°C, 7 h; cooling to room temp., filtered, addn. of n-pentane, crystn. within 5 d;elem. anal.;

DOI:10.1002/(SICI)1521-3749(200002)626:2<574::AID-ZAAC574>3.0.CO;2-V

Reference yield: 60.0%

(η(1)-benzyl)cobalt tetracarbonyl + (η(1)-(phenyl)acetyl)cobalt tetracarbonyl + (η(3)-benzyl)cobalt tricarbonyl (83267-99-6) → sodium tetracarbonyl cobaltate (14878-28-5) + Na(1+)*C6H5CH2C(O)Co(CO)3I(1-) = Na{C6H5CH2C(O)Co(CO)3I} (129174-90-9) + iodomethylbenzene (620-05-3) + benzyl alcohol (100-51-6,185532-71-2)

Guidance literature:

With sodium iodide; In tetrahydrofuran; hexane; CO atmosphere; evapn. soln. of Co-compds. in hexane, dissoln. (THF), addn. of NaI, reacting (1.5 h); not isolated; GC/MS and IR spectroscopy;

Reference yield:

Co2(CO)6(As(C6H5)3)2 (76586-43-1) → sodium tetracarbonyl cobaltate (14878-28-5) + Co(C4H8O)6(2+)*2Co(CO)4(1-)=(Co(C4H8O)6)(Co(CO)4)2 + triphenyl-arsane (603-32-7)

Guidance literature:

With Na-amalgam; In tetrahydrofuran;

upstream raw materials:

(η(3)-benzyl)cobalt tricarbonyl

Co₂(CO)6(As(C₆H₅)3)2

(methoxyacetyl)cobalt tetracarbonyl

sodium methylate

Downstream raw materials:

(CO)3Co((C₆H₅)2P)Pt(P(C₆H₅)3)2

(C₆H₅)2Pb(Co(CO)4)2

(C₆H₁₁)3PbCo(CO)4

(C₆H₅)2Sn{Co(CO)4}2