(η(3)-benzyl)cobalt tricarbonyl

Base Information

Chemical Name:(η(3)-benzyl)cobalt tricarbonyl
CAS No.:83267-99-6
Molecular Formula:C₁₀H₇CoO₃
Molecular Weight:234.157
Hs Code.:

Synonyms:(η(3)-benzyl)cobalt tricarbonyl

Suppliers and Price of (η(3)-benzyl)cobalt tricarbonyl

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (η(3)-benzyl)cobalt tricarbonyl

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (η(3)-benzyl)cobalt tricarbonyl

There total 5 articles about (η(3)-benzyl)cobalt tricarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 100-44-7
benzyl chloride

: (η(1)-benzyl)cobalt tetracarbonyl

: (η(1)-(phenyl)acetyl)cobalt tetracarbonyl

: 83267-99-6
(η(3)-benzyl)cobalt tricarbonyl

Guidance literature:: With sodium amalgam; In diethyl ether; Ar or CO atmosphere; treatment of soln. of Co-compd. in Et2O with Na/Hg filtn., addn. of org. compd., prolonged reaction (10-12 h); evapn., extn. (hexane), filtn., storring (CO atmosphere, -78°C), not isolated; IR spectroscopy;

Reference yield:

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 100-44-7
benzyl chloride

: (η(1)-benzyl)cobalt tetracarbonyl

: 83267-99-6
(η(3)-benzyl)cobalt tricarbonyl

Guidance literature:: With Na#Hg; In diethyl ether; Co2(CO)8 (2 mmol) was transformed into Na(Co(CO)4) in Et2O; org. compd.(3.8 mmol) was added to the filtered soln. under Ar; the mixt. was stirred for 8 h at room temp. and then the soln. was cooled to 0°C; Ar stream was bubbled through soln. for 6-10 h until the solvent was evapd.; the remaining dark oily product was extd. by n-hexane; the soln. was filtered and analyzed by IR;
DOI:10.1021/ja00272a031

Reference yield:

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 33100-27-5
15-crown-5

: 100-44-7
benzyl chloride

: (η(1)-benzyl)cobalt tetracarbonyl

: (η(1)-(phenyl)acetyl)cobalt tetracarbonyl

: 83267-99-6
(η(3)-benzyl)cobalt tricarbonyl

Guidance literature:: With sodium amalgam; In diethyl ether; Ar or CO atmosphere; treatment of soln. of Co-compd. in Et2O with Na/Hg filtn., addn. of 15-crown-5, addn. of benzyl chloride, stirring (1-1.5 h); not isolated; IR spectroscopy;