Technology Process of (triphos)RhPH(S2CO)
There total 1 articles about (triphos)RhPH(S2CO) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
tetrahydrofuran;
stirring of a mixture of Rh-compd. and Cu-compd. in THF at room temp. for 1 h (N2); pptn. of crystals, fitration from the mother liquor, additional crop by addn. of C2H5OH to the mother liquor, collection, washing, drying under N2; elem. anal.;
- Guidance literature:
-
With
H2;
In
tetrahydrofuran;
byproducts: C6H6; bubbling H2 through a suspension of Rh-complex in THF for 1 h; collection, washing, drying under N2, by-product detd. by GC;
- Guidance literature:
-
With
NaB(C6H5)4; HSO3CF3;
In
ethanol; dichloromethane;
byproducts: C6H6, COS; neat HSO3CF3 is syringed into a stirred soln. of Rh-complex in CH2Cl2 (Schenk flask) under N2, treatment of soln. with NaBPh4 in C2H5OH; collection, washing, drying under N2, detn. of byproducts by GC of gaseous phase;
