((triphos)Rh(μ-S)2Rh(triphos))(BPh4)2

Base Information

Chemical Name:((triphos)Rh(μ-S)2Rh(triphos))(BPh4)2
CAS No.:105139-43-3
Molecular Formula:2C₂₄H₂₀B*C₈₂H₇₈P₆Rh₂S₂
Molecular Weight:2157.77
Hs Code.:

Synonyms:((triphos)Rh(μ-S)2Rh(triphos))(BPh4)2

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Chemical Property of ((triphos)Rh(μ-S)2Rh(triphos))(BPh4)2

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Technology Process of ((triphos)Rh(μ-S)2Rh(triphos))(BPh4)2

There total 5 articles about ((triphos)Rh(μ-S)2Rh(triphos))(BPh4)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 117896-53-4
(triphos)RhPH(S₂CO)

: 105139-43-3
((triphos)Rh(μ-S)2Rh(triphos))(BPh4)2

Guidance literature:: With NaB(C₆H₅)4; HSO₃CF₃; In ethanol; dichloromethane; byproducts: C6H6, COS; neat HSO3CF3 is syringed into a stirred soln. of Rh-complex in CH2Cl2 (Schenk flask) under N2, treatment of soln. with NaBPh4 in C2H5OH; collection, washing, drying under N2, detn. of byproducts by GC of gaseous phase;

Reference yield: 78.0%

: 99955-64-3
{(triphos)Rh(S₂CO)}{BPh₄}

: 105139-43-3
((triphos)Rh(μ-S)2Rh(triphos))(BPh4)2

Guidance literature:: With NaB(C₆H₅)4; HSO₃CF₃ or; CH₃SO₃CF₃; In tetrahydrofuran; ethanol; byproducts: H2S, (CH3)2S, COS; neat HSO3CF3 or MeSO3CF3 is syringed into a stirred soln. of Rh-complex in THF (Schenk flask) under N2, treatment of soln. with NaBPh4 in C2H5OH; further byproduct; collection, washing, drying under N2, detn. of byproducts by GC of gaseous phase;

Reference yield: 72.0%

: 14104-20-2
silver tetrafluoroborate

: bis(ethylene)rhodium(I) chloride dimer

: 99955-64-3
((triphos)Rh(S₂CO))BPh₄

: 143-66-8
sodium tetraphenyl borate

: 22031-12-5
[2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]

: 105139-43-3
((triphos)Rh(μ-S)2Rh(triphos))(BPh4)2

Guidance literature:: In tetrahydrofuran; dichloromethane; byproducts: AgCl, CO; THF soln. of ((C2H4)2RhCl)2 and AgBF4 stirred for 1 h, AgCl filtered off, addn. of triphos and then soln. of ((triphos)Rh(S2CO))BPh4 in CH2Cl2, addn. of NaBPh4 in ethanol; evapn. of solvent; elem. anal.;
DOI:10.1021/ja00220a032