1-(4-(trifluoromethyl)phenyl)-3,3-bis(trifluoromethyl)-3H-2,1-benzoxabismole

Base Information

Chemical Name:1-(4-(trifluoromethyl)phenyl)-3,3-bis(trifluoromethyl)-3H-2,1-benzoxabismole
CAS No.:148419-42-5
Molecular Formula:C₁₆H₈BiF₉O
Molecular Weight:596.205
Hs Code.:

Synonyms:1-(4-(trifluoromethyl)phenyl)-3,3-bis(trifluoromethyl)-3H-2,1-benzoxabismole

Suppliers and Price of 1-(4-(trifluoromethyl)phenyl)-3,3-bis(trifluoromethyl)-3H-2,1-benzoxabismole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of 1-(4-(trifluoromethyl)phenyl)-3,3-bis(trifluoromethyl)-3H-2,1-benzoxabismole

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 1-(4-(trifluoromethyl)phenyl)-3,3-bis(trifluoromethyl)-3H-2,1-benzoxabismole

There total 4 articles about 1-(4-(trifluoromethyl)phenyl)-3,3-bis(trifluoromethyl)-3H-2,1-benzoxabismole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 143494-25-1
1-acetoxy-3,3-bis(trifluoromethyl)-3H-2,1-benzoxabismole

: 2786-01-8
(4-trifluoromethylphenyl)lithium

: 148419-42-5
1-(4-(trifluoromethyl)phenyl)-3,3-bis(trifluoromethyl)-3H-2,1-benzoxabismole

Guidance literature:: In diethyl ether; stirring (-78°C, 3 h); extn. (ether), recrystn. (acetone/ether), elem. anal.;

Reference yield: 53.0%

: 121882-75-5
(p-CF₃C₆H₄)3BiCl₂

: 70091-67-7
lithium 1,1,1,3,3,3-hexafluoro-2-(2-lithiophenyl)-2-propoxide

: 121882-73-3
3,3-bis(trifluoromethyl)-1,1,1-tris(p-(trifluoromethyl)-phenyl)-3H-2,1-benzoxabismole

: 148419-42-5
1-(4-(trifluoromethyl)phenyl)-3,3-bis(trifluoromethyl)-3H-2,1-benzoxabismole

: 109541-76-6
tris(4-(trifluoromethyl)phenyl)bismuthane

Guidance literature:: With NaCl; In tetrahydrofuran; hexane; N2; -78 ° C; addn. of triarylbismuth dichloride (or dibromide) to a solution of lithium hexafluoro propoxide; stirring for 4.5-8 h at -78 ° C;; quenching with aqueous NaCl; extraction with ether; drying (MgSO4) and solvent removal; product separation by flash chromy.; elem. anal. of the products;;
DOI:10.1021/om00029a047

Reference yield:

: 70091-67-7
lithium 1,1,1,3,3,3-hexafluoro-2-(2-lithiophenyl)-2-propoxide

: 148419-42-5
1-(4-(trifluoromethyl)phenyl)-3,3-bis(trifluoromethyl)-3H-2,1-benzoxabismole

Guidance literature:: Multi-step reaction with 3 steps

1: H₂O / diethyl ether

2: diethyl ether

3: diethyl ether

With H₂O; In diethyl ether;