70091-67-7Relevant academic research and scientific papers
Directed Dilithiation of Hexafluorocumyl Alcohol - Formation of a Reagent for the Facile Introduction of a Stabilizing Bidentate Ligand in Compounds of Hypervalent Sulfur (10-S-4), Phosphorus (10-P-5), Silicon (10-Si-5), and Iodine (10-I-3)
Perozzi, Edmund F.,Michalak, Ronald S.,Figuli, Garret D.,Stevenson III, William H.,Dess, Daniel B.,et al.
, p. 1049 - 1053 (1981)
The reaction of 1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanol (RFOH) with either sec-butyllithium or n-bulyllithium/N,N,N'N'-tetramethylethylenediamine (TMEDA) provides 3, a reagent for the facile introduction of a bidentate ligand which is partic
Stereomutation and apicophilicity of diastereomeric spirophosphoranes (10-P-5)
Nakamoto, Masaaki,Kojima, Satoshi,Matsukawa, Shiro,Yamamoto, Yohsuke,Akiba, Kin-Ya
, p. 441 - 452 (2002)
The apicophilicity for a series of monodentate groups were determined by deducing activation parameters of equilibration between diastereomeric spirophosphoranes bearing a Martin ligand and a modified Martin ligand. The equilibration was shown to be an in
One-step synthesis of unsymmetrical sulfides bearing hexafluorocumyl moiety
Zajac, Adrian,Drabowicz, Jozef
, p. 3287 - 3293 (2013/10/01)
A facile and convenient one-pot synthesis of novel unsymmetrical sulfides, 2′-alkylthio-and 2′-arylthio-1,1,1,3,3,3-hexafluoro-2-phenylpropan- 2-oles 1a-k, is presented. Physicochemical characterization; IR infrared; 1H, 13C, and su
