tert-butyl(((2S,3S)-2-((4-methoxybenzyl)oxy)-hex-5-en-3-yl)oxy)dimethylsilane

Base Information

Chemical Name:tert-butyl(((2S,3S)-2-((4-methoxybenzyl)oxy)-hex-5-en-3-yl)oxy)dimethylsilane
CAS No.:263761-20-2
Molecular Formula:C₂₀H₃₄O₃Si
Molecular Weight:350.574
Hs Code.:

Synonyms:tert-butyl(((2S,3S)-2-((4-methoxybenzyl)oxy)-hex-5-en-3-yl)oxy)dimethylsilane

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Chemical Property of tert-butyl(((2S,3S)-2-((4-methoxybenzyl)oxy)-hex-5-en-3-yl)oxy)dimethylsilane

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Technology Process of tert-butyl(((2S,3S)-2-((4-methoxybenzyl)oxy)-hex-5-en-3-yl)oxy)dimethylsilane

There total 5 articles about tert-butyl(((2S,3S)-2-((4-methoxybenzyl)oxy)-hex-5-en-3-yl)oxy)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 214892-50-9
(4S,5S)-4-hydroxy-5-(4-methoxybenzyloxy)-1-hexene

: 263761-20-2
tert-butyl(((2S,3S)-2-((4-methoxybenzyl)oxy)-hex-5-en-3-yl)oxy)dimethylsilane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 22 ℃; for 24h;
DOI:10.1002/(SICI)1521-3773(20000204)39:3<581::AID-ANIE581>3.0.CO;2-W

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: C₁₄H₂₀O₃

: 263761-20-2
tert-butyl(((2S,3S)-2-((4-methoxybenzyl)oxy)-hex-5-en-3-yl)oxy)dimethylsilane

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 0 - 25 ℃; for 22h;
DOI:10.3762/bjoc.14.274

Reference yield:

: 89238-99-3
O-(4-methoxybenzyl)-trichloroacetimidate

: 263761-20-2
tert-butyl(((2S,3S)-2-((4-methoxybenzyl)oxy)-hex-5-en-3-yl)oxy)dimethylsilane

Guidance literature:: Multi-step reaction with 4 steps

1: 82 percent / CF₃SO₃H / cyclohexane; CH₂Cl₂ / 0.75 h

2: DIBAL / various solvent(s); CH₂Cl₂ / 2.25 h / -78 °C

3: 84 percent / MgBr₂*OEt₂ / CH₂Cl₂ / -23 °C

4: 53.4 g / imidazole / dimethylformamide / 12.5 h / 23 °C

With 1H-imidazole; trifluorormethanesulfonic acid; diisobutylaluminium hydride; magnesium bromide; In dichloromethane; cyclohexane; N,N-dimethyl-formamide;
DOI:10.1021/jo015756a