(6R,11R,12R,E)-12-(2-(benzyloxy)ethyl)-14,14-diethyl-6-hydroxy-2,2,11-trimethyl-3,3-diphenyl-4,13-dioxa-3,14-disilahexadec-9-en-8-one

Base Information

Chemical Name:(6R,11R,12R,E)-12-(2-(benzyloxy)ethyl)-14,14-diethyl-6-hydroxy-2,2,11-trimethyl-3,3-diphenyl-4,13-dioxa-3,14-disilahexadec-9-en-8-one
CAS No.:1609272-74-3
Molecular Formula:C₄₀H₅₈O₅Si₂
Molecular Weight:675.069
Hs Code.:

Synonyms:(6R,11R,12R,E)-12-(2-(benzyloxy)ethyl)-14,14-diethyl-6-hydroxy-2,2,11-trimethyl-3,3-diphenyl-4,13-dioxa-3,14-disilahexadec-9-en-8-one

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Chemical Property of (6R,11R,12R,E)-12-(2-(benzyloxy)ethyl)-14,14-diethyl-6-hydroxy-2,2,11-trimethyl-3,3-diphenyl-4,13-dioxa-3,14-disilahexadec-9-en-8-one

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Technology Process of (6R,11R,12R,E)-12-(2-(benzyloxy)ethyl)-14,14-diethyl-6-hydroxy-2,2,11-trimethyl-3,3-diphenyl-4,13-dioxa-3,14-disilahexadec-9-en-8-one

There total 9 articles about (6R,11R,12R,E)-12-(2-(benzyloxy)ethyl)-14,14-diethyl-6-hydroxy-2,2,11-trimethyl-3,3-diphenyl-4,13-dioxa-3,14-disilahexadec-9-en-8-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 1609272-70-9
(R)-7-((tert-butyldiphenylsilyl)oxy)-6-hydroxyhept-2-en-4-one

: 1609272-73-2
(((3R,4R)-1-(benzyloxy)-4-methylhex-5-en-3-yl)oxy)triethylsilane

: 1609272-74-3
(6R,11R,12R,E)-12-(2-(benzyloxy)ethyl)-14,14-diethyl-6-hydroxy-2,2,11-trimethyl-3,3-diphenyl-4,13-dioxa-3,14-disilahexadec-9-en-8-one

Guidance literature:: With 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(iso-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methylene ruthenium(II) dichloride; In dichloromethane; at 45 ℃; for 48h; Inert atmosphere;
DOI:10.1002/anie.201400605

Reference yield: 79.0%

: 1609272-73-2
(((3R,4R)-1-(benzyloxy)-4-methylhex-5-en-3-yl)oxy)triethylsilane

: (R)-7-((tert-butyldiphenylsilyl)oxy)-6-hydroxyhept-2-en-4-one

: 1609272-74-3
(6R,11R,12R,E)-12-(2-(benzyloxy)ethyl)-14,14-diethyl-6-hydroxy-2,2,11-trimethyl-3,3-diphenyl-4,13-dioxa-3,14-disilahexadec-9-en-8-one

Guidance literature:: With C₂₉H₃₃Cl₂N₂O₃RuS; In dichloromethane; at 45 ℃; for 48h; Inert atmosphere;
DOI:10.1002/chem.201501491

Reference yield:

: 107033-46-5
(R)-(tert-butyldiphenylsilyloxy)methyloxirane

: 1609272-74-3
(6R,11R,12R,E)-12-(2-(benzyloxy)ethyl)-14,14-diethyl-6-hydroxy-2,2,11-trimethyl-3,3-diphenyl-4,13-dioxa-3,14-disilahexadec-9-en-8-one

Guidance literature:: Multi-step reaction with 3 steps

1: dicobalt octacarbonyl; carbon monoxide / ethyl acetate / 15 h / Inert atmosphere

2: tetrahydrofuran / 2 h / 0 °C / Inert atmosphere

3: 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(iso-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methylene ruthenium(II) dichloride / dichloromethane / 48 h / 45 °C / Inert atmosphere

With dicobalt octacarbonyl; 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(iso-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methylene ruthenium(II) dichloride; carbon monoxide; In tetrahydrofuran; dichloromethane; ethyl acetate;
DOI:10.1002/anie.201400605