methyl 7'-t-butyldimethylsiloxyabscisiate

Base Information

Chemical Name:methyl 7'-t-butyldimethylsiloxyabscisiate
CAS No.:134409-14-6
Molecular Formula:C₂₂H₃₆O₅Si
Molecular Weight:408.61
Hs Code.:

Synonyms:methyl 7'-t-butyldimethylsiloxyabscisiate

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Chemical Property of methyl 7'-t-butyldimethylsiloxyabscisiate

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Technology Process of methyl 7'-t-butyldimethylsiloxyabscisiate

There total 35 articles about methyl 7'-t-butyldimethylsiloxyabscisiate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 134409-13-5
methyl 5-(2-t-butyldimethylsiloxymethyl-4,4-ethylenedioxy-1-hydroxy-6,6-dimethylcyclohex-2-enyl)-3-methylpenta-2,4-dienoate

: 134409-14-6
methyl 7'-t-butyldimethylsiloxyabscisiate

Guidance literature:: With toluene-4-sulfonic acid; In acetone; for 1h; Yield given;
DOI:10.1016/S0040-4020(01)86392-4

Reference yield:

: 6153-05-5,105-29-3
(Z)-3-methylpent-2-en-4-ynol

: 134409-14-6,134524-19-9,134524-20-2
(2Z,4E)-5-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-1-hydroxy-6,6-dimethyl-4-oxo-cyclohex-2-enyl]-3-methyl-penta-2,4-dienoic acid methyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) n-BuLi / 1,) THF, dry ice-acetone bath -> 0 deg C (20 min); 2.) THF, -78 deg C -> r.t. (1 h)

2: 51 percent / bis(2-methoxyethoxy)aluminium hydride / tetrahydrofuran / 4 h / ethylene glycol / dry ice bath

3: 825 mg / MnO₂ / acetone / 1 h / Ambient temperature

4: MnO₂, NaCN / acetic acid / 2 h

5: p-toluenesulfonic acid / acetone / 1 h

With manganese(IV) oxide; n-butyllithium; sodium cyanide; sodium dihydro-bis-(2-methoxyethoxy)aluminate; toluene-4-sulfonic acid; In tetrahydrofuran; acetic acid; acetone;
DOI:10.1016/S0040-4020(01)86392-4

Reference yield:

: 6153-05-5,105-29-3
(Z)-3-methylpent-2-en-4-ynol

: 134409-14-6,134524-19-9,134524-20-2
(2Z,4E)-5-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-1-hydroxy-6,6-dimethyl-4-oxo-cyclohex-2-enyl]-3-methyl-penta-2,4-dienoic acid methyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) n-BuLi / 1,) THF, dry ice-acetone bath -> 0 deg C (20 min); 2.) THF, -78 deg C -> r.t. (1 h)

2: 51 percent / bis(2-methoxyethoxy)aluminium hydride / tetrahydrofuran / 4 h / ethylene glycol / dry ice bath

3: 825 mg / MnO₂ / acetone / 1 h / Ambient temperature

4: MnO₂, NaCN / acetic acid / 2 h

5: p-toluenesulfonic acid / acetone / 1 h

With manganese(IV) oxide; n-butyllithium; sodium cyanide; sodium dihydro-bis-(2-methoxyethoxy)aluminate; toluene-4-sulfonic acid; In tetrahydrofuran; acetic acid; acetone;
DOI:10.1016/S0040-4020(01)86392-4